Role of various moving walls on energy transfer rates via heat flow visualization during mixed convection in square cavities

Energy ◽  
2015 ◽  
Vol 82 ◽  
pp. 1-22 ◽  
Author(s):  
Monisha Roy ◽  
S. Roy ◽  
Tanmay Basak
2008 ◽  
Vol 2008 ◽  
pp. 1-5 ◽  
Author(s):  
A. Monguzzi ◽  
R. Tubino ◽  
F. Meinardi

The upconverted fluorescence generation in a solution of multicomponent organic systems has been studied as a function of the temperature to investigate the role of resonant energy transfer processes and of the molecular diffusion on the overall emission yield. The strong blue emission observed exciting the samples at 532 nm derives from a bimolecular triplet-triplet annihilation between 9,10 diphenylanthracene molecules, which produces singlet excited states from which the higher energy emission takes place. Diphenylanthracene excited triplet states are populated by energy transfer from a phosphorescent donor (Pt(II)octaethylporphyrin) which acts as excitation light harvesting. At low temperature, the experimental data on the efficiency of the transfer have been interpreted in the frame of a Dexter energy transfer in the Perrin approximation. At room temperature, the fast diffusion of the molecules has been found to be the main factor which affects the energy transfer rates and the overall photon upconversion efficiency.


Exacta ◽  
2008 ◽  
Vol 5 (1) ◽  
Author(s):  
André Felipe Henriques Librantz ◽  
Lilia Coronato Courrol ◽  
Laércio Gomes ◽  
Sonia Lícia Baldochi ◽  
Izilda Marcia Ranieri

In this paper, we present the energy transfer rates of YLF:Yb:Tm:Nd system, identifying the most important processes that lead to the thulium blue upconversion emission under excitation around 792 nm. The calculation of the rate equations system based on numerical method using Runge-Kutta method was employed for analyzing the population inversion between 1G4 and 3H4 states of Tm3+. Population inversion was achieved only in Yb:Nd:Tm doped YLF crystal, which exhibits a pumping rate threshold of 620 s-1. The Nd3+ absorption near 792 nm is very important because the excitation is rapidly transferred to Yb3+, that also interacts with Tm3+.


Exacta ◽  
2008 ◽  
Vol 5 (1) ◽  
Author(s):  
André Felipe Henriques Librantz ◽  
Lilia Coronato Courrol ◽  
Laércio Gomes ◽  
Sonia Lícia Baldochi ◽  
Izilda Marcia Ranieri

In this paper, we present the energy transfer rates of YLF:Yb:Tm:Nd system, identifying the most important processes that lead to the thulium blue upconversion emission under excitation around 792 nm. The calculation of the rate equations system based on numerical method using Runge-Kutta method was employed for analyzing the population inversion between 1G4 and 3H4 states of Tm3+. Population inversion was achieved only in Yb:Nd:Tm doped YLF crystal, which exhibits a pumping rate threshold of 620 s-1. The Nd3+ absorption near 792 nm is very important because the excitation is rapidly transferred to Yb3+, that also interacts with Tm3+.


2011 ◽  
Vol 35 (1) ◽  
pp. 15-27
Author(s):  
Zoran Ivić ◽  
Željko Pržulj

Adiabatic large polarons in anisotropic molecular crystals We study the large polaron whose motion is confined to a single chain in a system composed of the collection of parallel molecular chains embedded in threedimensional lattice. It is found that the interchain coupling has a significant impact on the large polaron characteristics. In particular, its radius is quite larger while its effective mass is considerably lighter than that estimated within the one-dimensional models. We believe that our findings should be taken into account for the proper understanding of the possible role of large polarons in the charge and energy transfer in quasi-one-dimensional substances.


ChemPhysChem ◽  
2011 ◽  
Vol 12 (8) ◽  
pp. 1499-1508 ◽  
Author(s):  
Florian A. Feist ◽  
Martin F. Zickler ◽  
Thomas Basché

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