Facile high yield, excellent catalytic performance of polyoxometalate-based lanthanide phosphine oxide complexes: Syntheses, structures, photocatalysis and THz spectra

A facile approach has been developed to fabricate hierarchical SAPO-34 with large intracrystalline meso/macropores and excellent catalytic performance in the MTO reaction.

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Fe3 Cluster Anchored on the C2N Monolayer for Efficient Electrochemical Nitrogen Fixation

Catalysts ◽

10.3390/catal10090974 ◽

2020 ◽

Vol 10 (9) ◽

pp. 974

Author(s):

Bing Han ◽

Haihong Meng ◽

Fengyu Li ◽

Jingxiang Zhao

Keyword(s):

Nitrogen Fixation ◽

First Principles ◽

Catalytic Performance ◽

Reduction Reaction ◽

First Principles Calculations ◽

Ammonia Gas ◽

Nitrogen Reduction ◽

Single Cluster ◽

Excellent Catalytic Performance ◽

Production Of Ammonia

Under the current double challenge of energy and the environment, an effective nitrogen reduction reaction (NRR) has become a very urgent need. However, the largest production of ammonia gas today is carried out by the Haber–Bosch process, which has many disadvantages, among which energy consumption and air pollution are typical. As the best alternative procedure, electrochemistry has received extensive attention. In this paper, a catalyst loaded with Fe3 clusters on the two-dimensional material C2N (Fe3@C2N) is proposed to achieve effective electrochemical NRR, and our first-principles calculations reveal that the stable Fe3@C2N exhibits excellent catalytic performance for electrochemical nitrogen fixation with a limiting potential of 0.57 eV, while also suppressing the major competing hydrogen evolution reaction. Our findings will open a new door for the development of non-precious single-cluster catalysts for effective nitrogen reduction reactions.

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Amino-functionalized Cu-MOF for efficient purification of methane from light hydrocarbons and excellent catalytic performance

Inorganic Chemistry Frontiers ◽

10.1039/c8qi01404c ◽

2019 ◽

Vol 6 (5) ◽

pp. 1152-1157 ◽

Cited By ~ 9

Author(s):

Xia Wang ◽

Xiurong Zhang ◽

Kai Zhang ◽

Xiaokang Wang ◽

Yutong Wang ◽

...

Keyword(s):

Catalytic Performance ◽

Light Hydrocarbons ◽

Excellent Catalytic Performance

Amino-functionalized Cu-MOF for the efficient purification of methane from light hydrocarbons and excellent catalytic performance.

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Ultrasound-assisted nanocasting fabrication and excellent catalytic performance of three-dimensionally ordered mesoporous chromia for the combustion of formaldehyde, acetone, and methanol

Applied Catalysis B Environmental ◽

10.1016/j.apcatb.2010.07.037 ◽

2010 ◽

Vol 100 (1-2) ◽

pp. 229-237 ◽

Cited By ~ 82

Author(s):

Yunsheng Xia ◽

Hongxing Dai ◽

Lei Zhang ◽

Jiguang Deng ◽

Hong He ◽

...

Keyword(s):

Catalytic Performance ◽

Ordered Mesoporous ◽

Ultrasound Assisted ◽

Excellent Catalytic Performance

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Glycerol acetalization over highly ordered mesoporous molybdenum dioxide: Excellent catalytic performance, recyclability and water-tolerance

Journal of Industrial and Engineering Chemistry ◽

10.1016/j.jiec.2021.12.007 ◽

2021 ◽

Author(s):

Gyoung Hee Hong ◽

Zhengyang Li ◽

Jin Seo Park ◽

Zhenghua Li ◽

Ki Yeong Kim ◽

...

Keyword(s):

Catalytic Performance ◽

Molybdenum Dioxide ◽

Water Tolerance ◽

Ordered Mesoporous ◽

Excellent Catalytic Performance

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Pt Modified Ni-Mo-based Hydrate as Bifunctional Electrocatalysts for Overall Water Splitting

New Journal of Chemistry ◽

10.1039/d1nj02046c ◽

2021 ◽

Author(s):

Yayu Guan ◽

Yuyu Liu

Keyword(s):

Water Splitting ◽

Catalytic Performance ◽

Overall Water Splitting ◽

Bifunctional Electrocatalysts ◽

Excellent Catalytic Performance

Pt-modified Ni-Mo-based nanomaterials were prepared by a simple and effective method. The modified Ni-Mo-based materials exhibited excellent catalytic performance in KOH solution by adjusting the amount of Pt introduced. Due...

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