Near UV–visible light induced cationic photopolymerization reactions: A three component photoinitiating system based on acridinedione/silane/iodonium salt

2010 ◽  
Vol 46 (11) ◽  
pp. 2138-2144 ◽  
Author(s):  
Mohamad-Ali Tehfe ◽  
Jacques Lalevée ◽  
Fabrice Morlet-Savary ◽  
Nicolas Blanchard ◽  
Cédric Fries ◽  
...  
Keyword(s):  
Visible Light ◽  
Cationic Photopolymerization ◽  
Iodonium Salt ◽  
Uv Visible

scholarly journals Bis-chalcone derivatives derived from natural products as near-UV/visible light sensitive photoinitiators for 3D/4D printing

2021 ◽  
Author(s):  
Hong Chen ◽  
Guillaume Noirbent ◽  
Shaohui Liu ◽  
Damien Brunel ◽  
Bernadette Graff ◽  
...  
Keyword(s):  
Natural Products ◽  
Visible Light ◽  
4D Printing ◽  
Chalcone Derivatives ◽  
Iodonium Salt ◽  
Uv Visible ◽  
First Time

Four series of novel bis-chalcone compounds with excellent performances have been synthesized and examined for the first time as photoinitiators in combination with an amine and an iodonium salt for the FRP of acrylates and the CP of EPOX.

Four structural diversity MOF-photocatalysts readily prepared for the degradation of the methyl violet dye under UV-visible light

2021 ◽  
Author(s):  
Lu Lu ◽  
Jun Wang ◽  
Chuncheng Shi ◽  
Yanchun Sun ◽  
Weiping Wu ◽  
...  
Keyword(s):  
Visible Light ◽  
Methyl Violet ◽  
Structural Diversity ◽  
Uv Visible ◽  
Photocatalytic Performances

The photocatalytic results demonstrated that all of them displayed efficient photocatalytic performances towards the degradation of methyl violet. The mechanism has been proposed.

scholarly journals Studies on the substrate-dependent photocatalytic properties of Cu2O heterojunctions

RSC Advances ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 4935-4941
Author(s):  
Riza Ariyani Nur Khasanah ◽  
Hui-Ching Lin ◽  
Hsiang-Yun Ho ◽  
Yen-Ping Peng ◽  
Tsong-Shin Lim ◽  
...  
Keyword(s):  
Visible Light ◽  
Light Absorption ◽  
Charge Separation ◽  
Spectral Response ◽  
Photocatalytic Properties ◽  
Visible Light Absorption ◽  
Uv Visible

Cu2O/TNA/Ti photoanode showed spectral response outperformed Cu2O/Ti and Cu2O/FTO photocathodes. Cu2O/TNA/Ti showed better spectral response than that of TNA/Ti, ascribed to UV-visible light absorption of Cu2O, not to charge separation enhancement.

scholarly journals Panchromatic Copper Complexes for Visible Light Photopolymerization

Photochem ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 167-189
Author(s):  
Alexandre Mau ◽  
Guillaume Noirbent ◽  
Céline Dietlin ◽  
Bernadette Graff ◽  
Didier Gigmes ◽  
...  
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Radical Polymerization ◽  
Copper Complexes ◽  
Free Radical Polymerization ◽  
Photoluminescence Properties ◽  
System Formation ◽  
Iodonium Salt ◽  
Visible Light Photopolymerization ◽  
Cationic Polymerizations

In this work, eleven heteroleptic copper complexes were designed and studied as photoinitiators of polymerization in three-component photoinitiating systems in combination with an iodonium salt and an amine. Notably, ten of them exhibited panchromatic behavior and could be used for long wavelengths. Ferrocene-free copper complexes were capable of efficiently initiating both the radical and cationic polymerizations and exhibited similar performances to that of the benchmark G1 system. Formation of acrylate/epoxy IPNs was also successfully performed even upon irradiation at 455 nm or at 530 nm. Interestingly, all copper complexes containing the 1,1′-bis(diphenylphosphino)ferrocene ligand were not photoluminescent, evidencing that ferrocene could efficiently quench the photoluminescence properties of copper complexes. Besides, these ferrocene-based complexes were capable of efficiently initiating free radical polymerization processes. The ferrocene moiety introduced in the different copper complexes affected neither their panchromatic behaviors nor their abilities to initiate free radical polymerizations.

Plasmonic and non-plasmonic contributions on photocatalytic activity of Au-TiO2 thin film under mixed UV–visible light

2020 ◽  
Vol 389 ◽  
pp. 125613 ◽  
Author(s):  
Salih Veziroglu ◽  
Marie Ullrich ◽  
Majid Hussain ◽  
Jonas Drewes ◽  
Josiah Shondo ◽  
...  
Keyword(s):  
Thin Film ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Tio2 Thin Film ◽  
Uv Visible

Hydrothermal Synthesis of Nanosized Titania Photocatalysts Using Novel Water-Soluble Titanium Complexes

2007 ◽  
Vol 124-126 ◽  
pp. 723-726 ◽  
Author(s):  
Makoto Kobayashi ◽  
Koji Tomita ◽  
Valery Petrykin ◽  
Shu Yin ◽  
Tsugio Sato ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Specific Surface ◽  
Single Phase ◽  
Visible Region ◽  
Water Soluble ◽  
No Oxidation ◽  
Nano Particles ◽  
Titanium Complexes ◽  
Uv Visible

Highly crystalline titania nano-particles were synthesized by hydrothermal method using novel stable water-soluble titanium complexes. It was confirmed that single phase anatase, rutile and brookite, which can be rarely synthesized as a single phase, can be obtained by varying the ligand in the complex and pH of the aqueous solution. TEM observations and BET specific surface area measurements had shown that these samples consisted of nanosized particles of 5~200 nm and had high specific surface areas of 25~150 m2/g. According to UV-visible diffuse reflectance spectra, these titania samples absorbed light in the visible region (λ > 400 nm). Photocatalytic activities in NO oxidation reaction exhibited by synthesized titania powders under the irradiation by UV- visible light were higher than the activity of the commercial TiO2 photocatalyst P25 (Degussa). Especially, under illumination by only visible light of above 510 nm wavelength, photocatalytic activity of the obtained specimens exceeded that of P25 more than four times. We also clearly demonstrated that single phase brookite had high photocatalytic activity for NO oxidation.

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