Oxidation chemistry of C–H bond by mononuclear iron complexes derived from tridentate ligands containing phenolato function

2017 ◽  
Vol 464 ◽  
pp. 195-203 ◽  
Author(s):  
Atul Choudhary ◽  
Ovender Singh ◽  
Udai P. Singh ◽  
Kaushik Ghosh
Keyword(s):  
Iron Complexes ◽  
Tridentate Ligands ◽  
Mononuclear Iron ◽  
Oxidation Chemistry

Molecular and Electronic Structures of Mononuclear Iron Complexes Using Strongly Electron-Donating Ligands and their Oxidized Forms

2008 ◽  
Vol 47 (15) ◽  
pp. 6804-6824 ◽  
Author(s):  
Julia B. H. Strautmann ◽  
Serena DeBeer George ◽  
Eberhard Bothe ◽  
Eckhard Bill ◽  
Thomas Weyhermüller ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Iron Complexes ◽  
Mononuclear Iron

Mononuclear Iron Complexes with Tetraazadentate Ligands as Water Oxidation Catalysts

2016 ◽  
Vol 2016 (20) ◽  
pp. 3262-3268 ◽  
Author(s):  
Gayatri Panchbhai ◽  
Wangkheimayum Marjit Singh ◽  
Biswanath Das ◽  
Reuben T. Jane ◽  
Anders Thapper
Keyword(s):  
Water Oxidation ◽  
Iron Complexes ◽  
Oxidation Catalysts ◽  
Mononuclear Iron

scholarly journals Coordination and conformational isomers in mononuclear iron complexes with pertinence to the [FeFe] hydrogenase active site

2014 ◽  
Vol 43 (11) ◽  
pp. 4537-4549 ◽  
Author(s):  
Andreas Orthaber ◽  
Michael Karnahl ◽  
Stefanie Tschierlei ◽  
Daniel Streich ◽  
Matthias Stein ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Active Site ◽  
Iron Complexes ◽  
Computational Studies ◽  
Mononuclear Iron ◽  
Conformational Isomers ◽  
Ligand Modification ◽  
Fe Complexes ◽  
Ir Spectroscopic

6 Fe complexes of the type [Fe(X-bdt)(PR2NPh2)(CO)] were prepared and the possibility to tune their electronic properties by ligand modification was demonstrated. IR spectroscopic and computational studies suggest that the compounds exist as a mixture of isomers in solution.

scholarly journals Substituent dependence on the spin crossover behaviour of mononuclear Fe(ii) complexes with asymmetric tridentate ligands

2019 ◽  
Vol 48 (10) ◽  
pp. 3231-3236 ◽  
Author(s):  
Ryo Saiki ◽  
Haruka Miyamoto ◽  
Hajime Sagayama ◽  
Reiji Kumai ◽  
Graham N. Newton ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Spin Crossover ◽  
Tridentate Ligands ◽  
Mononuclear Iron

Three mononuclear iron(ii) complexes with novel asymmetric tridentate ligands were synthesized and their structures and magnetic properties were studied. The ligand substituents were found to affect the supramolecular packing and spin-crossover properties of the complexes.

Mononuclear iron(iii) complexes of tridentate ligands with efficient nuclease activity and studies of their cytotoxicity

2015 ◽  
Vol 13 (47) ◽  
pp. 11445-11458 ◽  
Author(s):  
Nidhi Tyagi ◽  
Ajanta Chakraborty ◽  
Udai P. Singh ◽  
Partha Roy ◽  
Kaushik Ghosh
Keyword(s):  
Cell Lines ◽  
Dna Cleavage ◽  
Mcf7 Cell ◽  
Nuclease Activity ◽  
Oh Radicals ◽  
Dna Interactions ◽  
Tridentate Ligands ◽  
Mononuclear Iron ◽  
Chelated Iron

Mono- and bis-chelated iron(iii) complexes derived from phenolato-based tridentate ligands have been synthesised and characterized. These complexes show electrostatic DNA interactions and efficient DNA cleavage via OH˙ radicals, and induce cytotoxicity in MCF7 cell lines.

A new system for cyclohexane functionalization employing iron(iii) catalysts and trichloroisocyanuric acid

2017 ◽  
Vol 41 (20) ◽  
pp. 11498-11502 ◽  
Author(s):  
Clicia A. Gomes ◽  
Leonardo M. Lube ◽  
Christiane Fernandes ◽  
Roberto W. A. Franco ◽  
Jackson A. L. C. Resende ◽  
...  
Keyword(s):  
Iron Complexes ◽  
Mononuclear Iron ◽  
Trichloroisocyanuric Acid ◽  
New System

Herein, dinuclear and mononuclear iron complexes were investigated as catalysts in the reaction of cyclohexane chlorination employing trichloroisocyanuric acid as oxidant.

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