Abstract
The multi-phase field model of grain competitive growth during directional solidification of alloy was established, solving multi-phase field models for thin interface layer thickness conditions, grain boundary evolution and grain elimination during the competitive growth of SCN-0.24wt% camphor model alloy bi-crystals were investigated, the effects of different crystal orientations and pulling velocities on grain boundary microstructure evolution were quantitatively analyzed. The results show that in the competitive growth of convergent bi-crystals, when favorably oriented dendrites are in the same direction as the heat flow and the pulling speed is too large, the orientation angle of the bi-crystal from small to large is the normal elimination phenomenon of the favorably oriented dendrite blocking the unfavorably oriented dendrite, and the grain boundary is along the growth direction of the favorably oriented dendrite, and when the pulling speed becomes small, the grain boundary shows the anomalous elimination phenomenon of the unfavorably oriented dendrite eliminating the favorably oriented dendrite. In the process of competitive growth of divergent bi-crystal, when the growth direction of favorably oriented dendrites is the same as the heat flow direction and the orientation angle of unfavorably oriented grains is small, the frequency of new spindles of favorably oriented grains is significantly higher than that of unfavorably oriented grains, and as the orientation angle of unfavorably oriented dendrites becomes larger, the unfavorably oriented grains are more likely to have stable secondary dendritic arms, which in turn develop new primary dendritic arms to occupy the liquid phase grain boundary space, but the grain boundary direction is still parallel to favorably oriented dendrites. In addition, the tertiary dendritic arms on the developed secondary dendritic arms may also be blocked by the surrounding lateral branches from further developing into nascent main axes, this blocking of the tertiary dendritic arms has a random nature, which can have an impact on the generation of nascent primary main axes in the grain boundaries.
Grain growth competition during thin-sample directional solidification of dendritic microstructures: A phase-field study