Comparison of Pt and Pd anode catalysts supported on nanocrystalline Ru–SnO2 for ethanol oxidation in fuel cell applications

Author(s):  
Milica P. Marčeta Kaninski ◽  
Zoran V. Šaponjić ◽  
Mihajlo D. Mudrinić ◽  
Dubravka S. Milovanović ◽  
Boris M. Rajčić ◽  
...  
2010 ◽  
Vol 55 (20) ◽  
pp. 6073-6080 ◽  
Author(s):  
A.D. Modestov ◽  
M.R. Tarasevich ◽  
V.Ya. Filimonov ◽  
E.S. Davydova

Author(s):  
Rajib Adhikary ◽  
Dipankar Sarkar ◽  
Manabendra Mukherjee ◽  
Jayati Datta

The present investigation deals with Pd NPs casted over Fe2O3 support in formulating Pd/Fe2O3 catalyst with a complete non Pt and non carbon approach toward accomplishing electro-catalysis of ethanol oxidation...


2021 ◽  
Vol 118 (43) ◽  
pp. e2107332118
Author(s):  
Xian Wang ◽  
Yang Li ◽  
Ying Wang ◽  
Hao Zhang ◽  
Zhao Jin ◽  
...  

The CO electrooxidation is long considered invincible in the proton exchange membrane fuel cell (PEMFC), where even a trace level of CO in H2 seriously poisons the anode catalysts and leads to huge performance decay. Here, we describe a class of atomically dispersed IrRu-N-C anode catalysts capable of oxidizing CO, H2, or a combination of the two. With a small amount of metal (24 μgmetal⋅cm−2) used in the anode, the H2 fuel cell performs its peak power density at 1.43 W⋅cm−2. When operating with pure CO, this catalyst exhibits its maximum current density at 800 mA⋅cm−2, while the Pt/C-based cell ceases to work. We attribute this exceptional catalytic behavior to the interplay between Ir and Ru single-atom centers, where the two sites act in synergy to favorably decompose H2O and to further facilitate CO activation. These findings open up an avenue to conquer the formidable poisoning issue of PEMFCs.


2019 ◽  
Vol 235 ◽  
pp. 473-479 ◽  
Author(s):  
Omar Muneeb ◽  
Emily Do ◽  
Desiree Boyd ◽  
Josh Perez ◽  
John L. Haan
Keyword(s):  

2019 ◽  
Vol 44 (58) ◽  
pp. 30719-30731 ◽  
Author(s):  
S. Themsirimongkon ◽  
T. Sarakonsri ◽  
S. Lapanantnoppakhun ◽  
J. Jakmunee ◽  
S. Saipanya

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