A metal–organic framework (Zr–MA) was designed to serve as high-performance solid electrolyte in quasi-solid lithium metal batteries. Both the high-density thiol groups and narrow channels in framework contributed to the improved ion transport.
A quasi-solid-state electrolyte based on LATP-PVDF-HFP nanofiber matrix and gel is proposed. The fabricated battery exhibits a good discharge capacity of 146.6 mA h g−1 at 2C, while the capacity retention can reach 97% after 300 cycles at 0.5C.
A borate-rich polymer electrolyte with near-single ion conduction and a stable solid electrolyte interphase for high performance lithium metal batteries.