scholarly journals Statistical entropy analysis as tool for circular economy: Proof of concept by optimizing a lithium-ion battery waste sieving system

2019 ◽  
Vol 212 ◽  
pp. 1568-1579 ◽  
Author(s):  
O. Velázquez Martínez ◽  
K.G. Van Den Boogaart ◽  
M. Lundström ◽  
A. Santasalo-Aarnio ◽  
M. Reuter ◽  
...  
2021 ◽  
Vol 13 (6) ◽  
pp. 3553
Author(s):  
Philippe Nimmegeers ◽  
Alexej Parchomenko ◽  
Paul De Meulenaere ◽  
Dagmar R. D’hooge ◽  
Paul H. M. Van Steenberge ◽  
...  

Multilevel statistical entropy analysis (SEA) is a method that has been recently proposed to evaluate circular economy strategies on the material, component and product levels to identify critical stages of resource and functionality losses. However, the comparison of technological alternatives may be difficult, and equal entropies do not necessarily correspond with equal recyclability. A coupling with energy consumption aspects is strongly recommended but largely lacking. The aim of this paper is to improve the multilevel SEA method to reliably assess the recyclability of plastics. Therefore, the multilevel SEA method is first applied to a conceptual case study of a fictitious bag filled with plastics, and the possibilities and limitations of the method are highlighted. Subsequently, it is proposed to extend the method with the computation of the relative decomposition energies of components and products. Finally, two recyclability metrics are proposed. A plastic waste collection bag filled with plastic bottles is used as a case study to illustrate the potential of the developed extended multilevel SEA method. The proposed extension allows us to estimate the recyclability of plastics. In future work, this method will be refined and other potential extensions will be studied together with applications to real-life plastic products and plastic waste streams.


Recycling ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 26
Author(s):  
Jonas Henschel ◽  
Maximilian Mense ◽  
Patrick Harte ◽  
Marcel Diehl ◽  
Julius Buchmann ◽  
...  

The lithium-ion battery is the most powerful energy storage technology for portable and mobile devices. The enormous demand for lithium-ion batteries is accompanied by an incomplete recycling loop for used lithium-ion batteries and excessive mining of Li and transition metals. The hyperaccumulation of plants represents a low-cost and green technology to reduce environmental pollution of landfills and disused mining regions with low environmental regulations. To examine the capabilities of these approaches, the hyperaccumulation selectivity of Alyssum murale for metals in electrode materials (Ni, Co, Mn, and Li) was evaluated. Plants were cultivated in a conservatory for 46 days whilst soils were contaminated stepwise with dissolved transition metal species via the irrigation water. Up to 3 wt% of the metals was quantified in the dry matter of different plant tissues (leaf, stem, root) by means of inductively coupled plasma-optical emission spectroscopy after 46 days of exposition time. The lateral distribution was monitored by means of micro X-ray fluorescence spectroscopy and laser ablation-inductively coupled plasma-mass spectrometry, revealing different storage behaviors for low and high metal contamination, as well as varying sequestration mechanisms for the four investigated metals. The proof-of-concept regarding the phytoextraction of metals from LiNi0.33Co0.33Mn0.33O2 cathode particles in the soil was demonstrated.


2021 ◽  
Author(s):  
Rodrigo Serna-Guerrero ◽  
Omar Velazquez Martinez ◽  
Annukka Santasalo-Aarnio ◽  
Markus Reuter

2020 ◽  
Vol 161 ◽  
pp. 104925
Author(s):  
Alexej Parchomenko ◽  
Dirk Nelen ◽  
Jeroen Gillabel ◽  
Karl C. Vrancken ◽  
Helmut Rechberger

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