Influence of supporting electrolytes on the electron transfer and ion transfer coupling processes at a liquid/liquid interface

2017 ◽  
Vol 805 ◽  
pp. 32-38
Author(s):  
Chaoyue Gu ◽  
Xin Nie ◽  
Xin Zhang ◽  
Yifan Dong ◽  
Xianhao Zhang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Liquid Interface ◽  
Ion Transfer ◽  
Coupling Processes

Probing Electron-Transfer and Ion-Transfer Coupling Processes at Liquid/Liquid Interfaces with Pipette Electrodes

2016 ◽  
Vol 3 (12) ◽  
pp. 2153-2159 ◽  
Author(s):  
Xin Zhang ◽  
Haomin Wang ◽  
Celeste Morris ◽  
Chaoyue Gu ◽  
Mingzhi Li ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Ion Transfer ◽  
Liquid Interfaces ◽  
Coupling Processes

Voltammetric interpretation of ion transfer coupled with electron transfer at a liquid/liquid interface

1991 ◽  
Vol 303 (1-2) ◽  
pp. 171-184 ◽  
Author(s):  
Kohji Maeda ◽  
Sorin Kihara ◽  
Mitsuko Suzuki ◽  
Masakazu Matsui
Keyword(s):  
Electron Transfer ◽  
Liquid Interface ◽  
Ion Transfer

Studies of Electron-Transfer and Charge-Transfer Coupling Processes at a Liquid/Liquid Interface by Double-Barrel Micropipet Technique

2003 ◽  
Vol 75 (23) ◽  
pp. 6593-6601 ◽  
Author(s):  
Yong Chen ◽  
Zhao Gao ◽  
Fei Li ◽  
Liaohai Ge ◽  
Meiqin Zhang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Liquid Interface ◽  
Coupling Processes

The dehydrogenation of 1,4-dihydronaphthalene by tetrachloro-p-benzoquinone

1976 ◽  
Vol 54 (14) ◽  
pp. 2261-2265 ◽  
Author(s):  
Z. M. Hashish ◽  
I. M. Hoodless
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Reaction Rate ◽  
Second Order ◽  
Charge Transfer Complexes ◽  
Ion Transfer ◽  
Hydride Ion ◽  
Rate Determining Step ◽  
Hydride Ion Transfer

The dehydrogenation of 1,4-dihydronaphthalene by tetrachloro-p-benzoquinone in phenetole solution has been investigated. The present work does not fully confirm earlier studies which report that the reaction follows second-order kinetics and that the hydride ion transfer is rate determining. In the investigations described in this paper second-order kinetics are only observed in the later stages of the reaction and a 1:1 stoichiometry of the reactants in the process is not obtained. Substitution of tritium in the 1,4-positions of the hydrocarbon appears to not significantly affect the reaction rate. The present results indicate that charge-transfer complexes are formed in the reaction and it is suggested that electron transfer within these complexes could be the rate-determining step in the dehydrogenation.

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