Multinuclear NMR spectroscopy, photophysical, electrochemical and DNA-binding properties of fluorinated 1,8-naphthyridine-based boron heterocycles

2018 ◽  
Vol 205 ◽  
pp. 8-14 ◽  
Author(s):  
Helio G. Bonacorso ◽  
Tainara P. Calheiro ◽  
Bernardo A. Iglesias ◽  
Carolina Hahn da Silveira ◽  
Eufrânio N. da Silva Júnior ◽  
...  
2008 ◽  
Vol 61 (5) ◽  
pp. 376 ◽  
Author(s):  
Lifeng Tan ◽  
Hui Chao ◽  
Junjie Fei ◽  
Guojun Su ◽  
Sheng Zhang ◽  
...  

The new ligand MDPZ (MDPZ = 7,7′-methylenedioxyphenyldipyrido[3,2-a:2′,3′-c]-phenazine and its RuII complex [Ru(bpy)2(MDPZ)]2+ (phen = 1,10-phenanthroline) was synthesized and characterized by elemental analysis, mass spectrometry, and 1H NMR spectroscopy. The DNA-binding properties of [Ru(bpy)2(MDPZ)]2+ were investigated by different spectrophotometric methods and viscosity measurements. The results suggest that the complex binds to CT-DNA through intercalation, and can enantioselectively interact with CT-DNA. Although the [Ru(bpy)2(MDPZ)]2+ complex does not show the characteristics of a molecular ‘light switch’ for DNA, [Ru(phen)2(MDPZ)]2+ may serve as a sensitive luminescent probe for DNA. Also, when irradiated at 365 nm, the complex promotes the photocleavage of pBR 322 DNA.


1989 ◽  
Vol 264 (31) ◽  
pp. 18433-18439 ◽  
Author(s):  
F R Taylor ◽  
E P Shown ◽  
E B Thompson ◽  
A A Kandutsch

2021 ◽  
pp. 116191
Author(s):  
Hieronimus W. Kava ◽  
Wai Y. Leung ◽  
Anne M. Galea ◽  
Vincent Murray

1991 ◽  
Vol 266 (2) ◽  
pp. 1281-1288 ◽  
Author(s):  
M Brenowitz ◽  
N Mandal ◽  
A Pickar ◽  
E Jamison ◽  
S Adhya

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