Electrical and magnetic properties of La0.7Ca0.3Mn0.9Co0.1O3 locating at a threshold of the first- and second-order phase transitions

AbstractWe use exact recursion relations to study the magnetic properties of the half-integer mixed spin-5/2 and spin-3/2 Blume-Capel Ising ferromagnetic system on the two-fold Cayley tree that consists of two sublattices A and B. Two positive crystal-field interactions Δ1 and Δ2 are considered for the sublattice with spin-5/2 and spin-3/2 respectively. For different coordination numbers q of the Cayley tree sites, the phase diagrams of the model are presented with a special emphasis on the case q = 3, since other values of q reproduce similar results. First, the T = 0 phase diagram is illustrated in the (D A = Δ1/J,D B = Δ2/J) plane of reduced crystal-field interactions. This diagram shows triple points and coexistence lines between thermodynamically stable phases. Secondly, the thermal variation of the magnetization belonging to each sublattice for some coordination numbers q are investigated as well as the Helmoltz free energy of the system. First-order and second-order phase transitions are found. The second-order phase transitions become sharper and sharper when D A or D B increases. The first-order transitions only exist for some appropriate non-zero values of D A and/or D B. The corresponding transition lines never connect to the second-order transition lines. Thus, the non-existence of tricritical points remains one of the key features of the present model. The magnetic exponent β 0 of the model is estimated and found to be ¼ at small values of D A = D B = D and β 0 = ½ at large values of D. At intermediate values of D, there is a crossover region where the magnetic exponent displays interesting behaviours.

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Origin of the Structural Phase Transitions and the Anomalous Electrical and Magnetic Properties of the Magnetic Metal NaV6O11

Journal of the American Chemical Society ◽

10.1021/ja953508o ◽

1996 ◽

Vol 118 (16) ◽

pp. 3951-3958 ◽

Cited By ~ 12

Author(s):

Dong-Kyun Seo ◽

Myung-Hwan Whangbo

Keyword(s):

Magnetic Properties ◽

Phase Transitions ◽

Structural Phase ◽

Structural Phase Transitions ◽

Electrical And Magnetic Properties ◽

Magnetic Metal

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AEM analysis of crystallization in Ti-based amorphous alloys

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100075142 ◽

1983 ◽

Vol 41 ◽

pp. 270-271

Author(s):

A.R. Pelton ◽

A.F. Marshall ◽

Y.S. Lee

Keyword(s):

Magnetic Properties ◽

Amorphous Alloys ◽

Amorphous Materials ◽

Isothermal Annealing ◽

Amorphous Matrix ◽

Nucleation And Growth ◽

Current Interest ◽

Amorphous Films ◽

Electrical And Magnetic Properties

Amorphous materials are of current interest due to their desirable mechanical, electrical and magnetic properties. Furthermore, crystallizing amorphous alloys provides an avenue for discerning sequential and competitive phases thus allowing access to otherwise inaccessible crystalline structures. Previous studies have shown the benefits of using AEM to determine crystal structures and compositions of partially crystallized alloys. The present paper will discuss the AEM characterization of crystallized Cu-Ti and Ni-Ti amorphous films.Cu60Ti40: The amorphous alloy Cu60Ti40, when continuously heated, forms a simple intermediate, macrocrystalline phase which then transforms to the ordered, equilibrium Cu3Ti2 phase. However, contrary to what one would expect from kinetic considerations, isothermal annealing below the isochronal crystallization temperature results in direct nucleation and growth of Cu3Ti2 from the amorphous matrix.

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