Effect of conducting composite polypyrrole/polyaniline coatings on the corrosion resistance of type 304 stainless steel for bipolar plates of proton-exchange membrane fuel cells

2008 ◽  
Vol 182 (2) ◽  
pp. 524-530 ◽  
Author(s):  
Y.J. Ren ◽  
C.L. Zeng
2013 ◽  
Vol 573 ◽  
pp. 87-93 ◽  
Author(s):  
Yan Jie Ren ◽  
Jian Chen ◽  
Jian Jun He ◽  
Chao Liu Zeng

Polypyrrole coating doped with dodecylsulfate anions was electrodeposited by cyclic voltammetry and constant current technique on type 304 stainless steel used for bipolar plates of a proton-exchange membrane fuel cell from a basic solution of 0.2M pyrrole monomer solution containing dodecylsulfate sodium as supporting electrolyte. The morphology and corrosion performance of Ppy coated samples were investigated. Microscopic observations showed that the polypyrrole synthesized by constant current technique present a more dense constitution. Electrochemical measurements in 0.1M HCl solution showed that the polypyrrole synthesized by constant current technique provided better protection for the stainless steel.


RSC Advances ◽  
2015 ◽  
Vol 5 (79) ◽  
pp. 64466-64470 ◽  
Author(s):  
S. Pugal Mani ◽  
C. Anandan ◽  
N. Rajendran

In the present study, an attempt has been made to increase the corrosion resistance of 316L stainless steel (SS) bipolar plates (Bp) through electrochemical nitridation using a nitrate bearing electrolyte solution of 0.1 M HNO3 and 0.5 M KNO3.


2014 ◽  
Vol 905 ◽  
pp. 167-170 ◽  
Author(s):  
Yeon Jae Kim ◽  
Dong Hyun Kim ◽  
Jung Soo Kim ◽  
Jae Ho Jang ◽  
Uoo Chang Jung ◽  
...  

Chemical converted graphene (CCG) were coated on 316L stainless steel as a bipolar plate which is a component of proton exchange membrane fuel cell (PEMFC) by electro spray coating (ESC). Scanning electron microscope (SEM) and X-ray diffraction (XRD) were used to examine the thickness and surface properties of coating layer. Electrochemical potentiodynamic test was conducted in acidic atmosphere (0.1N H2SO4+2ppm F-) at 80°C using Versastat 4 and analysis program for corrosion resistance measurement. After packing bipolar plates for PEMFC stack, the electrical performances of graphite, bare SS316L and graphene coated SS316L bipolar plates were evaluated by PEMFC evaluating device. The chemical converted graphene was founded on the surface of coated SS316L, and the thickness was 12μm. Graphene coated bipolar plate showed high corrosion resistance of 1.32×10-7A/cm2beside bare SS316L bipolar plate. In electrical performance evaluation, the graphene coated bipolar plate was shown 0.978V on Voc and 0.5A/m2on the reduction potential (0.6V). Although the electrical performance of the graphene coated bipolar plate is lower than graphite bipolar plate, the thickness and weight is lower than graphite bipolar plate. These advantages can enable the PEMFC system more efficiently and economically.


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