Experimental and modeling study on water dynamic transport of the proton exchange membrane fuel cell under transient air flow and load change

2010 ◽  
Vol 195 (19) ◽  
pp. 6629-6636 ◽  
Author(s):  
Shuguo Qu ◽  
Xiaojin Li ◽  
Changchun Ke ◽  
Zhi-Gang Shao ◽  
Baolian Yi
Author(s):  
Andres Munoz ◽  
Abhijit Mukherjee

Water management still remains a challenge for proton exchange membrane fuel cells. Byproduct water formed in the cathode side of the membrane is wicked to the air supply channel through the gas diffusion layer. Water emerges into the air supply channel as droplets, which are then removed by the air stream. When the rate of water production is higher than the rate of water removal, droplets start to accumulate and coalesce with each other forming slugs consequently clogging the channels and causing poor fuel cell performance. It has been shown in previous experiments that rendering the channels hydrophobic or super-hydrophobic cause water droplets to be removed faster, not allowing time to coalesce, and therefore making channels less prone to flooding. In this numerical study we analyze water droplet growth and detachment from a simulated hydrophobic air supply channel inside a proton exchange membrane (PEM) fuel cell. In these numerical simulations the Navier-Stokes equations are solved using the SIMPLER method coupled with the level set technique in order to track the liquid-vapor interface. The effect of the gravity field acting in the −y, −x, and +x directions was examined for an array of water flow rates and air flow rates. Detachment times and diameters were computed. The results showed no significant effect of the gravity field acting in the three different directions as expected since the Bond and Capillary numbers are relatively small. The maximum variations in detachment time and diameter were found to be 8.8 and 4.2 percent, respectively, between the horizontal channel and the vertical channel with gravity acting in the negative x direction, against the air flow. Droplet detachment was more significantly affected by the air and water flow rates.


2009 ◽  
Vol 192 (1) ◽  
pp. 185-189 ◽  
Author(s):  
Radu Mustata ◽  
Luis Valiño ◽  
Félix Barreras ◽  
María Isabel Gil ◽  
Antonio Lozano

Energy ◽  
2022 ◽  
Vol 238 ◽  
pp. 121949
Author(s):  
Huicui Chen ◽  
Zhao Liu ◽  
Xichen Ye ◽  
Liu Yi ◽  
Sichen Xu ◽  
...  

Author(s):  
Hsiao-Kang Ma ◽  
Shih-Han Huang ◽  
Ya-Ting Cheng ◽  
Chen-Chiang Yu ◽  
Chrung Guang Hou ◽  
...  

Previous theoretical studies have shown that piezoelectric proton exchange membrane fuel cells (PZT-PEMFCs) might solve water flooding problems and increase cell performance. The innovative design of PZT-PEMFCs results in more oxygen being compressed into the catalyst layer. This enhances the electrochemical reaction and the current density, especially at a high PZT vibration frequency (64 Hz). In this investigation, a single, valveless PZT-PEMFC experimental fuel cell is built. The results are then compared with those of previous theoretical studies. This study includes an analysis of PZT vibration frequencies, and cell operation temperatures. A Nafion 212 membrane with a reaction area of 2 cm × 2 cm is used to measure the voltage and average current density under different temperatures and vibration frequencies. When the PZT device moves upward and increases the chamber volume, a diffuser directs most of the air to the outlet. In the valveless PZT-PEMFC, both a nozzle and diffuser are used. This innovative design may direct air flow into the cathode channel through the diffuser and prevent air backflow. The nozzle/diffuser design in this study can direct a single directional air flow without valves. The experimental results indicate that the direction in which the cell is mounted have a negligible effect on cell performance due to air flow through the nozzle. The diffuser is not influenced by gravity. The optimal operating temperature for the PZT-PEMFC of this study is 50°C, as higher temperatures dry out the membrane electrode assembly (MEA). The optimal vibration frequency of the PZT-PEMFC is 180Hz, as higher frequencies cause more air intake and solve the problem of water flooding in the cathode channel. This study also concludes that the innovative design of PZT-PEMFCs may equal the performance of an open cathode stack configuration and can be applied in a fuel cell stack without an external air supply device.


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