Fuel cell catalyst layers containing short-side-chain perfluorosulfonic acid ionomers

2011 ◽  
Vol 196 (1) ◽  
pp. 179-181 ◽  
Author(s):  
Jennifer Peron ◽  
Dave Edwards ◽  
Mark Haldane ◽  
Xiaoyan Luo ◽  
Yongming Zhang ◽  
...  
2011 ◽  
Vol 196 (15) ◽  
pp. 6168-6176 ◽  
Author(s):  
Chao Lei ◽  
Dmitri Bessarabov ◽  
Siyu Ye ◽  
Zhong Xie ◽  
Steven Holdcroft ◽  
...  

2015 ◽  
Vol 275 ◽  
pp. 384-391 ◽  
Author(s):  
Young-Chul Park ◽  
Katsuyoshi Kakinuma ◽  
Hiroyuki Uchida ◽  
Masahiro Watanabe ◽  
Makoto Uchida

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 78
Author(s):  
Nana Zhao ◽  
Zhiqing Shi ◽  
Francois Girard

Optimization of the ionomer materials in catalyst layers (CLs) which sometimes is overlooked has been equally crucial as selection of the membranes in membrane electrode assembly (MEA) for achieving a superior performance in proton exchange membrane fuel cells (PEMFCs). Four combinations of the MEAs composed of short-side-chain (SSC) and long-side-chain (LSC) perfluorosulfonic acid (PFSA) polymers as membrane and ionomer materials have been prepared and tested under various temperatures and humidity conditions, aiming to investigate the effects of different side chain polymer in membranes and CLs on fuel cell performance. It is discovered that SSC PFSA polymer used as membrane and ionomer in CL yields better fuel cell performance than LSC PFSA polymer, especially at high temperature and low RH conditions. The MEA with the SSC PFSA employed both as a membrane and as an ionomer in cathode CL demonstrates the best cell performance amongst the investigated MEAs. Furthermore, various electrochemical diagnoses have been applied to fundamentally understand the contributions of the different resistances to the overall cell performance. It is illustrated that the charge transfer resistance (Rct) made the greatest contribution to the overall cell resistance and then membrane resistance (Rm), implying that the use of the advanced ionomer in CL could lead to more noticeable improvement in cell performance than only the substitution as the membrane.


Desalination ◽  
2006 ◽  
Vol 193 (1-3) ◽  
pp. 398-404 ◽  
Author(s):  
M.G. De Angelis ◽  
S. Lodge ◽  
M. Giacinti Baschetti ◽  
G.C. Sarti ◽  
F. Doghieri ◽  
...  

2018 ◽  
Vol 165 (11) ◽  
pp. F1012-F1018 ◽  
Author(s):  
Scott A. Mauger ◽  
K. C. Neyerlin ◽  
Ami C. Yang-Neyerlin ◽  
Karren L. More ◽  
Michael Ulsh

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