Investigation of carbon supported Pd–Cu nanoparticles as anode catalysts for direct borohydride fuel cell

Dataset includes Direct Borohydride Fuel Cell (DBFC) impedance and polarization test in anode with Pd/C, Pt/C and Pd decorated Ni–Co/rGO catalysts. In fact, different concentration of Sodium Borohydride (SBH), applied voltages and various anode catalysts loading with explanation of experimental details of electrochemical analysis are considered in data. Voltage, power density and resistance of DBFC change as a function of weight percent of SBH (%), applied voltage and amount of anode catalyst loading that are evaluated by polarization and impedance curves with using appropriate equivalent circuit of fuel cell. Can be stated that interpretation of electrochemical behavior changes by the data of related cell is inevitable, which can be useful in simulation, power source investigation and depth analysis in DB fuel cell researches.

Download Full-text

Studies of electrochemical performance of carbon supported Pt–Cu nanoparticles as anode catalysts for direct borohydride–hydrogen peroxide fuel cell

Journal of Power Sources ◽

10.1016/j.jpowsour.2011.08.063 ◽

2011 ◽

Vol 196 (23) ◽

pp. 9924-9930 ◽

Cited By ~ 27

Author(s):

Lanhua Yi ◽

Benan Hu ◽

Yunfeng Song ◽

Xianyou Wang ◽

Guishan Zou ◽

...

Keyword(s):

Hydrogen Peroxide ◽

Fuel Cell ◽

Electrochemical Performance ◽

Cu Nanoparticles ◽

Anode Catalysts

Download Full-text

The use of polypyrrole modified carbon-supported cobalt hydroxide as cathode and anode catalysts for the direct borohydride fuel cell

Journal of Power Sources ◽

10.1016/j.jpowsour.2009.03.006 ◽

2009 ◽

Vol 192 (2) ◽

pp. 385-390 ◽

Cited By ~ 57

Author(s):

Hai Ying Qin ◽

Zi Xuan Liu ◽

Li Qiang Ye ◽

Jing Ke Zhu ◽

Zhou Peng Li

Keyword(s):

Fuel Cell ◽

Cobalt Hydroxide ◽

Anode Catalysts ◽

Direct Borohydride Fuel Cell

Download Full-text

High Performance Anode Catalysts for the Direct Borohydride Fuel Cell

ECS Meeting Abstracts ◽

10.1149/ma2008-02/4/468 ◽

2008 ◽

Keyword(s):

Fuel Cell ◽

High Performance ◽

Anode Catalysts ◽

Direct Borohydride Fuel Cell

Download Full-text

Experimental Dataset of Electrochemical Efficiency of a Direct Borohydride Fuel Cell (DBFC) with Pd/C, Pt/C and Pd Decorated Ni–Co/rGO Anode Catalysts

10.26434/chemrxiv.12174438.v1 ◽

2020 ◽

Author(s):

Sarmin Hamidi ◽

Sadra Sabouri ◽

Sepand Haghighi ◽

Kasra Askari

Keyword(s):

Fuel Cell ◽

Weight Percent ◽

Electrochemical Analysis ◽

Catalyst Loading ◽

Behavior Changes ◽

Anode Catalysts ◽

Direct Borohydride Fuel Cell ◽

Related Cell ◽

Depth Analysis ◽

Polarization Test

Dataset includes Direct Borohydride Fuel Cell (DBFC) impedance and polarization test in anode with Pd/C, Pt/C and Pd decorated Ni–Co/rGO catalysts. In fact, different concentration of Sodium Borohydride (SBH), applied voltages and various anode catalysts loading with explanation of experimental details of electrochemical analysis are considered in data. Voltage, power density and resistance of DBFC change as a function of weight percent of SBH (%), applied voltage and amount of anode catalyst loading that are evaluated by polarization and impedance curves with using appropriate equivalent circuit of fuel cell. Can be stated that interpretation of electrochemical behavior changes by the data of related cell is inevitable, which can be useful in simulation, power source investigation and depth analysis in DB fuel cell researches.

Download Full-text

CO tolerance and CO oxidation at Pt and Pt–Ru anode catalysts in fuel cell with polybenzimidazole–H3PO4 membrane

Electrochimica Acta ◽

10.1016/j.electacta.2010.05.068 ◽

2010 ◽

Vol 55 (20) ◽

pp. 6073-6080 ◽

Cited By ~ 47

Author(s):

A.D. Modestov ◽

M.R. Tarasevich ◽

V.Ya. Filimonov ◽

E.S. Davydova

Keyword(s):

Fuel Cell ◽

Co Oxidation ◽

Anode Catalysts ◽

Co Tolerance

Download Full-text

Proton exchange membrane fuel cells powered with both CO and H2

Proceedings of the National Academy of Sciences ◽

10.1073/pnas.2107332118 ◽

2021 ◽

Vol 118 (43) ◽

pp. e2107332118

Author(s):

Xian Wang ◽

Yang Li ◽

Ying Wang ◽

Hao Zhang ◽

Zhao Jin ◽

...

Keyword(s):

Fuel Cell ◽

Peak Power ◽

Proton Exchange Membrane ◽

Proton Exchange ◽

Single Atom ◽

Anode Catalysts ◽

Co Electrooxidation ◽

Co Activation ◽

Maximum Current ◽

Exchange Membrane

The CO electrooxidation is long considered invincible in the proton exchange membrane fuel cell (PEMFC), where even a trace level of CO in H2 seriously poisons the anode catalysts and leads to huge performance decay. Here, we describe a class of atomically dispersed IrRu-N-C anode catalysts capable of oxidizing CO, H2, or a combination of the two. With a small amount of metal (24 μgmetal⋅cm−2) used in the anode, the H2 fuel cell performs its peak power density at 1.43 W⋅cm−2. When operating with pure CO, this catalyst exhibits its maximum current density at 800 mA⋅cm−2, while the Pt/C-based cell ceases to work. We attribute this exceptional catalytic behavior to the interplay between Ir and Ru single-atom centers, where the two sites act in synergy to favorably decompose H2O and to further facilitate CO activation. These findings open up an avenue to conquer the formidable poisoning issue of PEMFCs.

Download Full-text