Impact of support layer pore size on performance of thin film composite membranes for forward osmosis

2015 ◽  
Vol 483 ◽  
pp. 25-33 ◽  
Author(s):  
Liwei Huang ◽  
Jeffrey R. McCutcheon
2019 ◽  
Vol 584 ◽  
pp. 20-45 ◽  
Author(s):  
Nawshad Akther ◽  
Sherub Phuntsho ◽  
Yuan Chen ◽  
Noreddine Ghaffour ◽  
Ho Kyong Shon

2017 ◽  
Vol 70 ◽  
pp. 64-78 ◽  
Author(s):  
Fang Li ◽  
Feng Zhao ◽  
Manhong Huang ◽  
Chunyan Ma ◽  
Bo Yang ◽  
...  

2013 ◽  
Vol 445 ◽  
pp. 220-227 ◽  
Author(s):  
Young Hoon Cho ◽  
Jungim Han ◽  
Sungsoo Han ◽  
Michael D. Guiver ◽  
Ho Bum Park

Membranes ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 842
Author(s):  
Senlin Gu ◽  
Bao Yuan ◽  
Bo Bai ◽  
Xin Tong ◽  
Luke A. O’Dell ◽  
...  

Hexagonal lyotropic liquid crystals (HLLC) with uniform pore size in the range of 1~5 nm are highly sought after as promising active separation layers of thin-film composite (TFC) membranes, which have been confirmed to be efficient for water purification. The potential interaction between an amphiphile-based HLLC layer and the substrate surface, however, has not been fully explored. In this research, hydrophilic and hydrophobic microporous polyvinylidene fluoride (PVDF) substrates were chosen, respectively, to prepare TFC membranes with the active layers templated from HLLC, consisting of dodecyl trimethylammonium bromide, water, and a mixture of poly (ethylene glycol) diacrylate and 2-hydroxyethyl methacrylate. The pore size of the active layer was found to decrease by about 1.6 Å compared to that of the free-standing HLLC after polymerization, but no significant difference was observable by using either hydrophilic or hydrophobic substrates (26.9 Å vs 27.1 Å). The water flux of the TFC membrane with the hydrophobic substrate, however, was higher than that with the hydrophilic one. A further investigation confirmed that the increase in water flux originated from a much higher porosity was due to the synergistic effect of the hydrophilic HLLC nanoporous material and the hydrophobic substrate.


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