Adsorption properties of a Pd/γ-Al2O3 catalyst using inverse gas chromatography

2004 ◽  
Vol 70 (1-3) ◽  
pp. 109-118 ◽  
Author(s):  
Eva Dı́az ◽  
Salvador Ordóñez ◽  
Aurelio Vega ◽  
José Coca
1987 ◽  
Vol 52 (3) ◽  
pp. 572-581 ◽  
Author(s):  
Miroslav M. Kopečni ◽  
Slobodan K. Milonjic ◽  
Wladyslaw Rudzinski ◽  
Jacek Jagiello

Adsorption isotherms of three adsorbates on the solid beads obtained from colloidal silica were determined by means of gas chromatography at low surface coverages, when lateral interactions between the adsorbed molecules are negligible. The influence of thermal pretreatment on the adsorption properties of the solids was investigated in the temperature range from 343 to 423 K, while the solids were heated between 523 K and 1 223 K. The thermodynamic parameters of adsorption have been determined and used to discuss the adsorbate-adsorbent interactions.


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