Pd complexes containing non-symmetrical diphosphines in the terpolymerization of ethene, propene and carbon monoxide

2007 ◽  
Vol 265 (1-2) ◽  
pp. 98-108 ◽  
Author(s):  
Antonella Leone ◽  
Sebastian Gischig ◽  
Giambattista Consiglio
Keyword(s):  
Carbon Monoxide ◽  
Pd Complexes

Asymetrical Dimer - allyl-palladiu Complexes II. Data from Infrared Spectra and Chemical Behaviour

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Maria Maganu ◽  
Filip Chiraleu ◽  
Constantin Draghici ◽  
Gheorghe Mihai
Keyword(s):  
Carbon Monoxide ◽  
Nmr Spectroscopy ◽  
1H Nmr ◽  
Infrared Spectra ◽  
Analytical Methods ◽  
1H Nmr Spectroscopy ◽  
Chemical Behaviour ◽  
The Asymmetry ◽  
Pd Complexes

The previous data obtained by 1H-NMR spectroscopy established the existence of an asymmetry of the bond between Pd and p-allylic groups, even in the p-allyl-Pd complexes dimers which are considered usually symmetric dimers. The asymmetry of the bond depends by the substitutes of the allylic group. Other analytical methods were investigated for additional proof of the obtained results. Thus, this paper discusses how this asymmetry would be reflected in the infrared spectra and in the reaction of the complexes with carbon monoxide.

Alternating copolymerization of ω-perfluoroalkyl-1-alkenes with carbon monoxide catalyzed by homogeneous and polymer-supported Pd-complexes

2001 ◽  
Vol 79 (5-6) ◽  
pp. 593-597
Author(s):  
Kyoko Nozaki ◽  
Fumitoshi Shibahara ◽  
Stephan Elzner ◽  
Tamejiro Hiyama
Keyword(s):  
Contact Angle ◽  
Carbon Monoxide ◽  
Water Contact Angle ◽  
Glass Surface ◽  
Water Contact ◽  
Solution State ◽  
Polymer Supported ◽  
Pd Complexes ◽  
Alternating Copolymerization ◽  
Supported Pd

Alternating copolymerization of fluorinated olefins (CnF2n+ 1)(CH2)mCH=CH2 (1) and carbon monoxide was carried out using cationic Pd(II)-(R,S)-BINAPHOS complexes (2) as catalysts. To obtain polymeric products sufficiently, existence of at least two methylenes in 1 were essential (m [Formula: see text] 2). The products thus obtained formed polyspiroketal (4) rather than polyketone (3), the structures being determined by solid- and solution-state NMR and IR analyses. The water contact angle was 108° for a sample of 4f when it was casted on a glass surface from C6F6 solution.Key words: copolymer, fluoroalkene, carbon monoxide, palladium, contact angle.

Carbon monoxide poisoning

2000 ◽  
Vol 12 (4) ◽  
pp. 354-357
Author(s):  
David R Smart ◽  
Paul D Mark
Keyword(s):  
Carbon Monoxide ◽  
Carbon Monoxide Poisoning
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