Wells-Dawson heteropoly acid immobilized inside the nanocages of SBA-16 with ship-in-a-bottle method: A new recoverable catalyst for the epoxidation of olefins

2016 ◽  
Vol 417 ◽  
pp. 81-88 ◽  
Author(s):  
M. Masteri-Farahani ◽  
M. Modarres
Keyword(s):  
Heteropoly Acid ◽  
Recoverable Catalyst ◽  
Epoxidation Of Olefins

Cu-Fe Spinels: First Heterogeneous and Magnetically Recoverable Catalyst for the Ferrier Rearrangement of 2-Nitroglycals

2019 ◽  
Vol 16 (6) ◽  
pp. 447-453 ◽  
Author(s):  
Leticia Lafuente ◽  
María Florencia Rochetti ◽  
Rodolfo Bravo ◽  
Leandro Sasiambarrena ◽  
Cintia C. Santiago ◽  
...  
Keyword(s):  
Reaction Products ◽  
External Magnet ◽  
Recoverable Catalyst ◽  
Ferrier Rearrangement ◽  
Magnetically Recoverable Catalyst

Cu-Fe spinels promoted the Ferrier rearrangement of 2-nitroglycals with several O-nucleophiles. 2,3-Unsaturated carbohydrate derivatives were prepared by the reaction of 3,4,6-tri-Oacetyl- 2-nitroglucal and alcohols in the presence of 5 % of CuFe2O4. After separation of the catalyst with an external magnet, the reaction products were obtained in good yields and high stereo and regioselectivity. Also, S- and heterocyclic C-3 substituted 2-nitro-endo-glycals could be prepared by this method.

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