Intermolecular interaction of organic solutes with protic [MIM][NO3] and aprotic [EMIM][NO3] ionic liquids

2020 ◽  
Vol 299 ◽  
pp. 112243 ◽  
Author(s):  
Artashes A. Khachatrian ◽  
Ilnaz T. Rakipov ◽  
Boris N. Solomonov ◽  
Sergey P. Verevkin
Keyword(s):  
Ionic Liquids ◽  
Intermolecular Interaction ◽  
Organic Solutes

scholarly journals Imidazolium Based Ionic Liquids: Unbiased Recovering of Vaporization Enthalpies from Infinite-Dilution Activity Coefficients

Molecules ◽  
2021 ◽  
Vol 26 (19) ◽  
pp. 5873
Author(s):  
Sergey P. Verevkin
Keyword(s):  
Ionic Liquids ◽  
General Formula ◽  
Activity Coefficients ◽  
Infinite Dilution ◽  
Reference Temperature ◽  
Organic Solutes ◽  
Imidazolium Cation ◽  
Infinite Dilution Activity Coefficients ◽  
Efficient Approach ◽  
Volatile Organic

We propose and test an efficient approach for the assessment of the enthalpies of vaporization of ionic liquids at the reference temperature 298.15 K. The approach is based on activity coefficients at infinite dilution of volatile organic solutes in ionic liquids bearing the imidazolium cation of the general formula [Cnmim][Anion].

Comparison between pyrrolidinium-based and imidazolium-based dicationic ionic liquids: intermolecular interaction, structural organization, and solute dynamics

2021 ◽  
Vol 23 (37) ◽  
pp. 21029-21041
Author(s):  
Amita Mahapatra ◽  
Manjari Chakraborty ◽  
Sahadev Barik ◽  
Moloy Sarkar
Keyword(s):  
Ionic Liquids ◽  
Steady State ◽  
Nmr Spectroscopy ◽  
Intermolecular Interaction ◽  
Structural Organization ◽  
Time Resolved Fluorescence ◽  
Time Resolved ◽  
Dicationic Ionic Liquids ◽  
The Difference ◽  
Solute Dynamics

This work investigates the difference in the microscopic behaviour of imidazolium and pyrrolidinium based ILs employing combined steady state and time-resolved fluorescence, EPR and NMR spectroscopy.

Sign in / Sign up

Export Citation Format

Share Document