Electrochemical evaluation and DFT calculations of aromatic sulfonohydrazides as corrosion inhibitors for XC38 carbon steel in acidic media

2019 ◽  
Vol 1198 ◽  
pp. 126898 ◽  
Author(s):  
Imane Ichchou ◽  
Lahcène Larabi ◽  
Houria Rouabhi ◽  
Yahia Harek ◽  
Amel Fellah
2015 ◽  
Vol 51 (3) ◽  
pp. 252-256 ◽  
Author(s):  
M. D. Plotnikova ◽  
I. A. Tiunov ◽  
A. A. Novikov ◽  
A. A. Khrenova ◽  
A. B. Shein

2021 ◽  
Vol 62 (4) ◽  
pp. 316-332
Author(s):  
El-Aziz Abd ◽  
Safaa Etaiw ◽  
Essam El-Waseef

The effect of the SCPs-[CuII(en)2] [CuI (CN)2]2. H2O] (SCP1) and {[H2DAB] [Cu4(CN)6].2H2O} (SCP2) as corrosion inhibitors for carbon steel (CS) was studied in 1.0M HCl solution. As the synthesized inhibitor dose increases, the inhibition productivity (%e) increases reaching to 90.3% and 89.9% at 21x10-6M dose for SCP2 and SCP1, respectively. This result evidenced by mass loss (ML) investigated at three different temperatures 25-35-45oC, while potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS), and electrochemical frequency modulation technique (EFM) were tested at 25°C. The synthesized inhibitors adsorbed on the CS surface physically allowing Henry isotherm. The results displayed that the synthesized inhibitors are excellent and their (%e) was significantly increased by raising the dose and decreased by raising the temperature. Polarization curves revealed that the synthesized inhibitors act as mixed type. The thermodynamic parameters were calculated and discussed. The protection was confirmed by the creation of the thin film of inhibitors precipitated on the surface of CS.


Author(s):  
A. S. Kalinina ◽  
◽  
I. S. Polkovnikov ◽  
A. B. Shein ◽  
◽  
...  

The inhibiting effect of some compositions of «Soling» series on low-carbon steel St3 in solutions of 5% and 15% HCl and 5% H2SO4 has been studied by the methods of polarization and gravimetric measurements. The protective action and the coefficient of inhibition of the corrosion process are calculated, the slopes of the Tafel sections in the cathode and anode regions of the polarization curves have been calculated. The influence of inhibitors on the kinetics of partial electrochemical reactions has been determined. The state of the surface of the samples has been estimated using micrographs. The high efficiency of inhibitors in acidic media has been shown.


Sign in / Sign up

Export Citation Format

Share Document