A New Organic–Inorganic Hybrid Compound (NH3(CH2)C6H4CO2H)[SnCl6]: Synthesis, crystal structure, vibrational, optical, magnetic properties and theoretical study

2021 ◽  
pp. 130129
Author(s):  
A. Kaiba ◽  
Faisal. Al Otaibi ◽  
Mohammed H. Geesi ◽  
Yassine Riadi ◽  
Talal A. Aljohani ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Theoretical Study ◽  
Hybrid Compound ◽  
Inorganic Hybrid

Crystal structure, thermochromic and magnetic properties of organic-inorganic hybrid compound: (C 7 H 7 N 2 S) 2 CuCl 4

2017 ◽  
Vol 1141 ◽  
pp. 93-98 ◽  
Author(s):  
Ashok K. Vishwakarma ◽  
Reema Kumari ◽  
Prasanna S. Ghalsasi ◽  
Navamoney Arulsamy
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
Compound C

Magnetic coupling in discrete cyano-bridged MnIII-FeIII motifs: Synthesis, crystal structure, magnetic properties and theoretical study

2010 ◽  
Vol 39 (20) ◽  
pp. 5028 ◽  
Author(s):  
Diana Visinescu ◽  
Luminita Marilena Toma ◽  
Joan Cano ◽  
Oscar Fabelo ◽  
Catalina Ruiz-Pérez ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Theoretical Study ◽  
Magnetic Coupling

scholarly journals Ionothermal synthesis and crystal structure of a new organic–inorganic hybrid compound:catena-poly[bis(1-ethyl-3-methylimidazolium) [hepta-μ-bromido-pentacuprate(I)]]

2014 ◽  
Vol 70 (11) ◽  
pp. 1021-1024
Author(s):  
Ljiljana Karanović ◽  
Dejan Poleti ◽  
Tamara Đorđević
Keyword(s):  
Crystal Structure ◽  
Three Dimensional ◽  
Mirror Plane ◽  
Site Symmetry ◽  
Small Contribution ◽  
Hybrid Compound ◽  
Coordination Environment ◽  
Synthesis And Crystal Structure ◽  
Inorganic Hybrid ◽  
Dimensional Network

A new organic–inorganic hybrid compound,catena-poly[bis(1-ethyl-3-methylimidazolium) [μ5-bromido-tri-μ3-bromido-tri-μ2-bromido-pentacuprate(I)]], {(C6H11N2)2[Cu5Br7]}n, has been obtained under ionothermal conditions from a reaction mixture containing Ba(OH)2·8H2O, Cu(OH)2·2H2O, As2O5, 1-ethyl-3-methylimidazolium bromide and distilled water. The crystal structure consists of complex [Cu5Br7]2−anions arranged in sinusoidal {[Cu5Br7]2−}nchains running along theaaxis, which are surrounded by 1-ethyl-3-methylimidazolium cations. Three of the five unique Br atoms and one of the three CuIatoms occupy special positions with half-occupancy (a mirror plane perpendicular to thebaxis, site symmetrym). The CuIions are in a distorted tetrahedral coordination environment, with four Br atoms at distances ranging from 2.3667 (10) to 2.6197 (13) Å, and an outlier at 3.0283 (12) Å, exceptionally elongated and with a small contribution to the bond-valence sum of only 6.7%. Short C—H...Br contacts build up a three-dimensional network. The Cu...Cu distances within the chain range from 2.8390 (12) to 3.0805 (17) Å, indicating the existence of weak CuI...CuIcuprophilic interactions.

scholarly journals Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

2015 ◽  
Vol 71 (11) ◽  
pp. 1345-1348
Author(s):  
Tamara J. Lukianova ◽  
Vasyl Kinzhybalo ◽  
Adam Pietraszko
Keyword(s):  
Crystal Structure ◽  
Aqueous Solution ◽  
Network Structure ◽  
Three Dimensional ◽  
Water Molecules ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
Dimensional Network

A new organic–inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[FeIII(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central FeIIIion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of intermolecular N—H...O and O—H...O interactions between cations, POMs, sulfate anions and non-coordinating water molecules creates a three-dimensional network structure.

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