Optical absorption of gamma-irradiated lithium-borate glasses doped with different transition metal oxides

2006 ◽  
Vol 382 (1-2) ◽  
pp. 340-351 ◽  
Author(s):  
S.Y. Marzouk ◽  
N.A. Elalaily ◽  
F.M. Ezz-Eldin ◽  
W.M. Abd-Allah





2008 ◽  
Vol 45 (sup5) ◽  
pp. 503-506 ◽  
Author(s):  
Jin-hyoung Bai ◽  
Jung Ryul Kim ◽  
Jin Young Chung ◽  
Jung Hoon Kim ◽  
Joo Ho Whang


1991 ◽  
Vol 119-121 (2) ◽  
pp. 669-674 ◽  
Author(s):  
K. D. Becker ◽  
T. He ◽  
F. Rau


2019 ◽  
Vol 503-504 ◽  
pp. 243-251 ◽  
Author(s):  
P. Sudhakar ◽  
A. Siva Sesha Reddy ◽  
Ya. Zhydachevskyy ◽  
M.G. Brik ◽  
A. Suchocki ◽  
...  






Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.



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