Chiral heterocyclic ligands. XVI: Synthesis and crystal structures of four metal complexes of a tridentate, biheterocyclic ligand derived from l-cysteine

Polyhedron ◽  
2010 ◽  
Vol 29 (10) ◽  
pp. 2220-2224 ◽  
Author(s):  
William Lewis ◽  
Peter J. Steel
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Heterocyclic Ligands

scholarly journals Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 199-227
Author(s):  
Young Hoon Lee ◽  
Jee Young Kim ◽  
Sotaro Kusumoto ◽  
Hitomi Ohmagari ◽  
Miki Hasegawa ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Weak Interactions ◽  
Dispersion Interactions ◽  
Derivatives Of

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.

Crystal Structures and Magnetic Properties of Hydrogen-Bonded Nitronyl Nitroxide Radicals and Their Metal Complexes

2002 ◽  
Vol 379 (1) ◽  
pp. 153-158 ◽  
Author(s):  
Mikio Ueda ◽  
Tomoyuki Mochida ◽  
Sachie Furukawa ◽  
Hideaki Suzuki ◽  
Hirosi Moriyama ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Hydrogen Bonded

Syntheses and Crystal Structures of Two New Pentaborates Templated by Transition-Metal Complexes

2014 ◽  
Vol 25 (5) ◽  
pp. 1295-1305 ◽  
Author(s):  
Qin Meng ◽  
Guo-Ming Wang ◽  
Huan He ◽  
Bai-Feng Yang ◽  
Guo-Yu Yang
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes
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