Synthesis, crystal structure and luminescence of Ag(I) coordination polymers based on a new sulfonate functionalized terpyridine derivative ligand

Polyhedron ◽  
2015 ◽  
Vol 91 ◽  
pp. 52-58 ◽  
Author(s):  
Sa-Sa Shen ◽  
Xiaofang Wang ◽  
Huai-Ming Hu ◽  
Fei Yuan ◽  
Fa-Xin Dong ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Crystal structure and characterization of two cadmium(II) coordination polymers with a multidentate N-donor tecton 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole

2013 ◽  
Vol 66 (3) ◽  
pp. 501-508 ◽  
Author(s):  
Yu-Fang Wang ◽  
Zhuo Li ◽  
Ying-Ying Li ◽  
Jian-She Zhao
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers

Synthesis, crystal structure, Hirshfeld surface analysis and theoretical investigation of polynuclear coordination polymers of Cobalt and Manganese complexes with nitrobenzene and pyrazine

2021 ◽  
pp. 131851
Author(s):  
Seadat Suliddin Hasanova ◽  
Lala Nizami Mamedova ◽  
Muhammad Ashfaq ◽  
Khurram Shahzad Munawar ◽  
Elman Muhammad Movsumov ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Surface Analysis ◽  
Theoretical Investigation ◽  
Coordination Polymers ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Manganese Complexes

Synthesis, crystal structure and properties of two 1D nano-chain coordination polymers constructed by lanthanide with pyridine-3,4-dicarboxylic acid and 1,10-phenanthroline

2008 ◽  
Vol 181 (5) ◽  
pp. 1017-1024 ◽  
Author(s):  
Hui-Hua Song ◽  
Ya-Juan Li ◽  
You Song ◽  
Zhan-Gang Han ◽  
Fang Yang
Keyword(s):  
Crystal Structure ◽  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Structure And Properties

Novel three-dimensional coordination polymers of lanthanides with sulfate and oxydiacetic acid

2013 ◽  
Vol 69 (12) ◽  
pp. 1503-1508 ◽  
Author(s):  
Thazhe Kootteri Prasad ◽  
M. V. Rajasekharan
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Lanthanide Oxides ◽  
Coordination Polyhedra ◽  
Hydrothermal Reactions ◽  
Lanthanide Cations ◽  
Trigonal Prismatic Coordination ◽  
Oxydiacetic Acid ◽  
Trigonal Prismatic

Three three-dimensional coordination polymers,viz.poly[[diaqua-μ4-oxydiacetato-di-μ4-sulfato-dipraseodymium(III)] hemihydrate], [Pr2(C4H4O5)(SO4)2(H2O)2]·0.5H2O, (I), poly[[diaquadi-μ3-oxydiacetato-μ3-sulfato-dineodymium(III)] 1.32-hydrate], [Nd2(C4H4O5)2(SO4)(H2O)2]·1.32H2O, (II), and poly[[diaquadi-μ3-oxydiacetato-μ3-sulfato-disamarium(III)] 1.32-hydrate], [Sm2(C4H4O5)2(SO4)(H2O)2]·1.32H2O, (III), were obtained by hydrothermal reactions of the respective lanthanide oxides and ZnSO4with oxydiacetic acid (odaH2). The Nd3+and Sm3+compounds form isomorphous crystal structures in which the lanthanide cations are nine-coordinate, having a tricapped trigonal prismatic coordination. The Pr3+compound has an entirely different crystal structure in which two types of coordination polyhedra are observed,viz.nine-coordinate (trigonal prism) and ten-coordinate (bicapped square antiprism). The sulfate anions show various coordination modes, one of which has only rarely been observed crystallographically to date.

Synthesis, Crystal Structure and Fluorescence of Two Novel Mixed-Ligand Cadmium Coordination Polymers with Different Structural Motifs

2003 ◽  
Vol 2003 (14) ◽  
pp. 2705-2710 ◽  
Author(s):  
Junhua Luo ◽  
Maochun Hong ◽  
Ruihu Wang ◽  
Rong Cao ◽  
Lei Han ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Mixed Ligand ◽  
Structural Motifs
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