Mercury(II) mixed ligand complexes of phosphines or amines with 2-cyanoamino thiophenolate ligands formed via monodeprotonation and carbon-sulfur bond cleavage of 2-aminobenzothiazole. X-ray crystal structures of [Hg(SC6H4NCN)(PPh3)]2 and [Hg(SC6H4NCN)(Ph2PCH2PPh2)]2

Polyhedron ◽  
2021 ◽  
pp. 115349
Author(s):  
Subhi A. Al-Jibori ◽  
Luma A. Al-Doori ◽  
Ahmed S.M. Al-Janabi ◽  
Mustafa A. Alheety ◽  
Christoph Wagner ◽  
...  
Polyhedron ◽  
1987 ◽  
Vol 6 (12) ◽  
pp. 2165-2168 ◽  
Author(s):  
Ray Jones ◽  
Thomas G. Purcell ◽  
David J. Williams ◽  
J.Derek Woollins

1985 ◽  
Vol 50 (6) ◽  
pp. 1383-1390
Author(s):  
Aref A. M. Aly ◽  
Ahmed A. Mohamed ◽  
Mahmoud A. Mousa ◽  
Mohamed El-Shabasy

The synthesis of the following mixed ligand complexes is reported: [Ni(phdtc)2(dpm)2], [Ni(phdtc)2(dpe)2], [Ni(phdtc)2(dpp)3], [Ni(1-naphdtc)2(dpm)2], [Ni(1-naphdtc)2], and [Ni(1-naphdtc)2(dpp)2], where phdtc = PhNHCSS-, 1-naphdtc = 1-NaPhNHCSS-, dpm = Ph2PCH2PPh2, dpe = Ph2P(CH2)2PPh2, and dpp = Ph2P(CH2)3PPh2. The complexes are characterised by microanalysis, IR and UV-Vis spectra, magnetic measurements, conductivity, X-ray powder diffraction, and thermal analysis. All the mixed ligand complexes are diamagnetic, and thus a square-planar or square-pyramidal (low-spin) structure was proposed for the present complexes.


2005 ◽  
Vol 631 (11) ◽  
pp. 2081-2085 ◽  
Author(s):  
María Pilar Brandi-Blanco ◽  
Duane Choquesillo-Lazarte ◽  
Josefa María González-Pérez ◽  
Alfonso Castiñeiras ◽  
Juan Niclós-Gutiérrez

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