Pd(II) and Ni(II) complexes containing ONNO tetradentate Schiff base ligand: Synthesis, crystal structure, spectral characterization, theoretical studies, and use of PdL as an efficient homogeneous catalyst for Suzuki–Miyaura cross-coupling reaction

Polyhedron ◽  
2021 ◽  
pp. 115622
Author(s):  
Hadi Kargar ◽  
Mehdi Fallah-Mehrjardi ◽  
Reza Behjatmanesh-Ardakani ◽  
Mehrnaz Bahadori ◽  
Majid Moghadam ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Spectral Characterization ◽  
Homogeneous Catalyst ◽  
Theoretical Studies ◽  
Tetradentate Schiff Base ◽  
Cross Coupling Reaction

scholarly journals A phosphine-free, atom-efficient cross-coupling reaction of triorganoindiums with acyl chlorides catalyzed by immobilization of palladium(0) in MCM-41

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42570-42578 ◽  
Author(s):  
Jiankang Miao ◽  
Bin Huang ◽  
Haiyi Liu ◽  
Mingzhong Cai
Keyword(s):  
Schiff Base ◽  
Schiff Base Complex ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Free Atom ◽  
Acyl Chlorides ◽  
Base Complex ◽  
Cross Coupling Reaction ◽  
Mcm 41

The phosphine-free, atom-efficient cross-coupling of triorganoindiums with acyl chlorides has been achieved using a recyclable MCM-41-immobilized palladium(0)–Schiff base complex.

Nickel(II) complex with an asymmetric tetradentate Schiff base ligand: synthesis, characterization, crystal structure, and DFT studies

2018 ◽  
Vol 71 (22) ◽  
pp. 3748-3762 ◽  
Author(s):  
Vajiheh Torabi ◽  
Hadi Kargar ◽  
Alireza Akbari ◽  
Reza Behjatmanesh-Ardakani ◽  
Hadi Amiri Rudbari ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Dft Studies ◽  
Tetradentate Schiff Base ◽  
Ligand Synthesis

scholarly journals A novel selective fluorescent chemosensor for Fe3+ ions based on phthalonitrile dimer: synthesis, analysis, and theoretical studies

2020 ◽  
Vol 44 (5) ◽  
pp. 1254-1264
Author(s):  
Shaya AL-RAQA ◽  
İpek ÖMEROĞLU ◽  
Doğan ERBAHAR ◽  
Mahmut DURMUŞ
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Interaction Mechanism ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Density Functional Theory Calculations ◽  
Theoretical Studies ◽  
Functional Theory ◽  
Cross Coupling Reaction ◽  
Ft Ir

Phenyl-4,4-di(3,6-dibutoxyphthalonitrile) (3) was synthesized by the reaction of 1,4-phenylenebisboronic acid (1) and 4-bromo-3,6-dibutoxyphthalonitrile (2), using Suzuki cross-coupling reaction. The newly synthesized compound (3) was characterized by FT-IR, MALDI-MS, ESI-MS, 1H-NMR, 13C-NMR, and 13C-DEPT-135-NMR. The fluorescence property of phenyl-4,4-di(3,6- dibutoxyphthalonitrile) (3) towards various metal ions was investigated by fluorescence spectroscopy, and it was observed thatthe compound (3) displayed a significantly ‘turn-off’ response to Fe3+, which was referred to 1:2 complex formation between ligand (3) and Fe3+. The compound was also studied via density functional theory calculations revealing the interaction mechanism of the molecule with Fe3+ ions.

Mono- and dioxido-vanadium(V) complexes of a tridentate ONO Schiff base ligand: Synthesis, spectral characterization, X-ray crystal structure, and anticancer activity

Polyhedron ◽  
2015 ◽  
Vol 93 ◽  
pp. 99-105 ◽  
Author(s):  
S. Yousef Ebrahimipour ◽  
Iran Sheikhshoaie ◽  
Anna Christin Kautz ◽  
Mojgan Ameri ◽  
Hamzeh Pasban-Aliabadi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Anticancer Activity ◽  
Schiff Base Ligand ◽  
Spectral Characterization ◽  
X Ray ◽  
Ligand Synthesis
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