Reversible addition–fragmentation chain transfer (RAFT) radical polymerization and the synthesis of water-soluble (co)polymers under homogeneous conditions in organic and aqueous media

2007 ◽  
Vol 32 (3) ◽  
pp. 283-351 ◽  
Author(s):  
Andrew B. Lowe ◽  
Charles L. McCormick
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Aqueous Media ◽  
Water Soluble ◽  
Reversible Addition

Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer:  The RAFT Process

1998 ◽  
Vol 31 (16) ◽  
pp. 5559-5562 ◽  
Author(s):  
John Chiefari ◽  
Y. K. (Bill) Chong ◽  
Frances Ercole ◽  
Julia Krstina ◽  
Justine Jeffery ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Reversible Addition ◽  
Living Free Radical Polymerization

Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization) Using Dithiocarbamates as Chain Transfer Agents

1999 ◽  
Vol 32 (21) ◽  
pp. 6977-6980 ◽  
Author(s):  
Roshan T. A. Mayadunne ◽  
Ezio Rizzardo ◽  
John Chiefari ◽  
Yen Kwong Chong ◽  
Graeme Moad ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Reversible Addition ◽  
Transfer Agents

scholarly journals Reversible addition fragmentation chain transfer polymerization - RAFT

2004 ◽  
Vol 58 (11) ◽  
pp. 514-520
Author(s):  
Milena Avramovic ◽  
Lynne Katsikas ◽  
Branko Dunjic ◽  
Ivanka Popovic
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
General Structure ◽  
Controlled Radical Polymerization ◽  
Molecular Structures ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

The fundamentals of controlled radical polymerization are presented in this review. The paper focuses on reversible addition fragmentation chain transfer (RAFT) polymerization. The mechanism and specifics of this type of polymerization are discussed, as are the possibilities of synthesizing complex macro-molecular structures. The synthesis and properties of RAFT agents, of the general structure Z-C(=S)-S-R, are presented.

Modification of Gold Surfaces with Water-Soluble (Co)polymers Prepared via Aqueous Reversible Addition−Fragmentation Chain Transfer (RAFT) Polymerization†

Langmuir ◽  
2003 ◽  
Vol 19 (14) ◽  
pp. 5559-5562 ◽  
Author(s):  
Brent S. Sumerlin ◽  
Andrew B. Lowe ◽  
Paul A. Stroud ◽  
Ping Zhang ◽  
Marek W. Urban ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Water Soluble ◽  
Gold Surfaces ◽  
Reversible Addition

Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates

Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1543-1551 ◽  
Author(s):  
Mao Chen ◽  
Honghong Gong ◽  
Yu Gu
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Atom Transfer ◽  
Reversible Addition ◽  
Controlled Living Radical Polymerization ◽  
Chain Transfer Polymerization ◽  
Semifluorinated Polymers

Fluorinated polymers are important materials for applications in many areas. This article summarizes the development of controlled/living radical polymerization (CRP) of semifluorinated (meth)acrylates, and briefly introduces their reaction mechanisms. While the classical CRP such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and nitroxide-mediated radical polymerization (NMP) have promoted the preparation of semifluorinated polymers with tailor-designed architectures, recent development of photo-CRP has led to unprecedented accuracy and monomer scope. We expect that synthetic advances will facilitate the engineering of advanced fluorinated materials with unique properties.1 Introduction2 Atom Transfer Radical Polymerization3 Reversible Addition-Fragmentation Chain Transfer Polymerization4 Nitroxide-Mediated Radical Polymerization5 Photo-CRP Mediated with Metal Complexes6 Metal-free Photo-CRP7 Conclusion

Light-responsive terpolymers based on polymerizable photoacids

2017 ◽  
Vol 8 (19) ◽  
pp. 2959-2971 ◽  
Author(s):  
Felix Wendler ◽  
Kilian R. A. Schneider ◽  
Benjamin Dietzek ◽  
Felix H. Schacher
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Synthesis And Characterization ◽  
Reversible Addition

We present the synthesis and characterization of amphiphilic terpolymers containing photoacids based on 1-naphthol using reversible addition fragmentation chain transfer radical polymerization (RAFT).

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