Grafting styrene onto poly(vinyl acetate) by free radical chain transfer reactions

2004 ◽  
Vol 61 (3) ◽  
pp. 387-395 ◽  
Author(s):  
Mircea Teodorescu ◽  
Mihai Dimonie ◽  
Constantin Draghici ◽  
Sever Şerban ◽  
Gabriel Vasilievici ◽  
...  
Keyword(s):  
Free Radical ◽  
Vinyl Acetate ◽  
Chain Transfer ◽  
Transfer Reactions ◽  
Radical Chain

Electron Transference in Free Radical Chain Transfer Reactions

Nature ◽  
1964 ◽  
Vol 202 (4933) ◽  
pp. 690-691 ◽  
Author(s):  
JAY K. KOCHI ◽  
DENNIS D. DAVIS
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
Transfer Reactions ◽  
Radical Chain

scholarly journals THE STRUCTURE OF BUTADIENE DIMERS PRODUCED BY A FREE-RADICAL CHAIN-TRANSFER MECHANISM

1957 ◽  
Vol 35 (12) ◽  
pp. 1467-1474 ◽  
Author(s):  
L. J. Gendron ◽  
R. V. V. Nicholls
Keyword(s):  
Free Radicals ◽  
Free Radical ◽  
Chain Transfer ◽  
Transfer Mechanism ◽  
The Other ◽  
Chain Transfer Agent ◽  
Radical Chain

Butadiene was dimerized by using acetyl peroxide as source of free radicals and chloroform as solvent and chain-transfer agent. The dimers were identified and their structures were determined by means of ozonolysis and oxidative hydrolysis. It was established that two dimers were produced in nearly equal amount. One dimer was formed only by 1,4-additions, the other only by 1,2-additions. This result implies that polybutadienes may be mixtures of two varieties: one variety resulting from 1,4-additions, the other from 1,2-additions.

scholarly journals Correction: Determining chemospecificity in reactions with chain transfer agent and corresponding radical via evaluation of molecular weight dependency of apparent comonomer reactivity ratios: free-radical copolymerization of vinyl acetate and dibutyl maleate

RSC Advances ◽  
2016 ◽  
Vol 6 (114) ◽  
pp. 112949-112949
Author(s):  
Seyed Saeid Rahdar ◽  
Mahdi Abdollahi ◽  
Ebrahim Ahmadi ◽  
Abbas Biglari
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Vinyl Acetate ◽  
Chain Transfer ◽  
Radical Copolymerization ◽  
Chain Transfer Agent ◽  
Reactivity Ratios ◽  
Free Radical Copolymerization ◽  
Dibutyl Maleate

Correction for ‘Determining chemospecificity in reactions with chain transfer agent and corresponding radical via evaluation of molecular weight dependency of apparent comonomer reactivity ratios: free-radical copolymerization of vinyl acetate and dibutyl maleate’ by Seyed Saeid Rahdar et al., RSC Adv., 2016, 6, 109759–109768.

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