A two-step procedure for the selection of innovative high temperature heat transfer fluids in solar tower power plants

Author(s):  
Giampaolo Manzolini ◽  
Gaia Lucca ◽  
Marco Binotti ◽  
Giovanni Lozza
Author(s):  
Cs. Singer ◽  
R. Buck ◽  
R. Pitz-Paal ◽  
H. Mu¨ller-Steinhagen

In commercial power plant technology, the market introduction of ultra supercritical (USC) steam cycle power plants with steam parameters around 350bar and 720°C is the next development step. USC steam cycles are also proposed to decrease the levelized electricity costs of future solar power towers due to their highly efficient energy conversion. A 55% thermal efficiency with decreased specific investment costs is within the potential of USC steam cycles. The required process parameters can be achieved using nickel based alloys in the solar receiver, the tubing and other plant components. For solar tower applications, appropriate high temperature heat transfer media (HTM), high temperature heat exchangers and storage options are additionally required. Using the current development for molten salt power towers (Solar Tres) as a reference, several tower concepts with USC power plants were compared. The ECOSTAR methodology provided by [1] was applied for predicting the cost reduction potential and the annual performance of these power tower concepts applying tubular receivers with various HTM. The considered HTM include alkali nitrate salts, alkali chloride salts and liquid metals such as a Bi-Pb eutectic, tin or sodium. For the assessment, an analytical model of the heat transfer in a parametric 360° cylindrical, tubular central receiver was developed to examine the receiver characteristics for different geometries. The sensitivity of the specific cost assumptions for the levelized electricity costs (LEC) was evaluated for each concept variation. No detailed evaluation was done for the thermal storage, but comparable costs were assumed for all cases. The results indicate a significant cost reduction potential for the liquid metal HTM processes.


Author(s):  
Kai Wang ◽  
Edgar Molina ◽  
Ghazal Dehghani ◽  
Ben Xu ◽  
Peiwen Li ◽  
...  

A group of eutectic ternary halide salts were surveyed and studied for the objective of developing a high temperature heat transfer fluid with a freezing point below 250°C and a low vapor pressure, below 1.0 atm, at temperatures up to 800°C. The studied salts include: 1) NaCl-KCl-ZnCl2 with a mole fractions of 18.6%-21.9%-59.5% and a melting point of tm=213°C; 2) NaCl-KCl-ZnCl2 with a mole fraction of 13.4%-33.7%-52.9% and a melting point of tm=204°C; and 3) NaCl-KCl-ZnCl2 with mole fraction of 13.8%-41.9%-44.3% and a melting point of tm=229 °C. Vapor pressures of these salts at different temperatures were experimentally obtained using an in-house developed test facility. The results show that vapor pressures of all the three eutectic molten salts are below 1.0 atm at a temperature of 800 °C. The salt of ZnCl2-KCl-NaCl in mole faction of 44.3%-41.9%-13.8% has lowest vapor pressure which is only about 1.0 atm even at a temperature of 900 °C. Viscosities of these salts were measured in the temperature range from after melting to 850°C. At low temperatures near their melting points of the salts, the viscosities are about 16 × 10−3Pa s, while at high temperatures above 700°C the viscosities are around 4 × 10−3Pa s, which is satisfactorily low to serve as heat transfer fluid for circulation in a CSP system. Both the vapor pressure and the viscosities of the studied three eutectic salts demonstrated satisfaction to serve as high temperature heat transfer fluids. Other thermal and transport properties of these salts are expected to be reported in the future for screening out a satisfactory high temperature heat transfer fluid.


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