Evaluation of the Potential of Nanofluids Containing Different Ag Nanoparticle Size Distributions for Enhanced Solar Energy Conversion in Hybrid Photovoltaic-thermal (PVT) Applications

Hybridising photovoltaic and photothermal technologies into a single system that can simultaneously deliver heat and power represents one of the leading strategies for generating clean energy at more affordable prices. In a hybrid photovoltaic-thermal (PVT) system, the capability to modulate the thermal and electrical power output is significantly influenced by the spectral properties of the heat transfer fluid utilised. In this study, we report on one of the first experimental evaluations of the capability of a multimodal silver nanofluid containing various particle shapes and particle sizes to selectively modulate the solar energy for PVT applications. The diverse set of particle properties led up to a 50.4% enhancement in the solar energy absorbed by the nanofluid over the 300 nm – 550 nm spectral region, where silicon is known to exhibit poor photovoltaic conversion performances. This improved substantially the absorption of solar energy, with an additional 18 – 129 W m-2 of thermal power being generated by the PVT system. Along with the advancements made in the thermal power output of the PVT system, a decrease of 4.7 – 36.6 W m-2 in the electrical power generated by the photovoltaic element was noted. Thus, for every ~11 W m-2 increase of thermal power achieved through the addition of the nanoparticles, a reduction of ~3 W m-2 in the ability to generate clean electricity was sustained by the PVT. Despite the energy trade-offs involved under the conditions of the nanofluid, the PVT system cumulatively harvested 405 W m-2 of solar energy, which amounts to a total conversion efficiency of 45%. Furthermore, the economics of the additional energy harvested through merging of the two systems was found to reach an enhancement of 77% under certain European conditions.

Demonstration and analysis of a steam reforming process driven with solar heat using molten salts as heat transfer fluid

Solar reforming of biogas or biomethane represents an example hydrogen production from the combination of renewable sources such as biomass and solar energy. Thanks to its relatively low-cost and flexibility, solar-reforming can represent a complementary source of hydrogen where/when the demand exceeds the green hydrogen availability from water electrolysis powered by PV or wind. Molten salts can be used as heat transfer fluid and heat storage medium in solar-driven steam reforming. The main units of the process have been developed at the pilot scale and experimentally tested in a molten salt experimental loop at ENEA-Casaccia research center: a molten salt heater and a molten salt membrane reformer. After experimental validation, techno-economic studies have been carried out to assess the solar reforming technology on commercial scale and exploitation opportunities have been analysed.

THEORETICAL INVESTIGATION OF HEAT PRODUCTION FEASIBILITY BY MEANS OF WIND MECHANICAL PLANTS

A widespread use of wind turbines can fully or partly provide energy for the consumers, but with due regards to certain investments and instability of energy generation. Technologies of using wind energy imply the conversion of the mechanical energy of a wind flow into the electrical or heat energy. The work is concerned with the estimation of the amount of heat in the process of heating liquid coolants and heat-transfer fluids when using wind mechanical plants. In the paper was made a numerical analysis of the temperature rise of the liquid which circulates in a closed loop of a gear-type pump, whose productivity is 3 l/m and which is driven by a wind turbine 5 kW of power capacity under a nominal wind speed of 7 m/s and under cycle duration of 2 s. The analysis showed that the temperature increased by 0.290 °К/s. If such wind speed is observed during one hour, the temperature of 100 kg of water will increase by 8.1°С. Heating of a heat-transfer fluid with a supply of mechanical energy to a working part can be achieved by a centrifugal fan. Assuming that the given process occurs without supplying and removing heat energy (it is adiabatic), for the capacity of 1.5 kW and under the revolution in a range of 1000….3000 r/m, the changes in temperature will range from 0.38 to 0.87 °К/s, but for the capacity of 7.5 kW and under 750 – 1500 r/m, the changes in temperature will range from 0.56 to 1.23 °К/s.

The Effect of Dynamic Cold Storage Packed Bed on Liquid Air Energy Storage in an Experiment Scale

Liquid air energy storage (LAES) is one of the most promising large-scale energy storage technologies for the decarburization of networks. When electricity is needed, the liquid air is utilized to generate electricity through expansion, while the cold energy from liquid air evaporation is stored and recovered in the air liquefaction process. The packed bed filled with rocks/pebbles for cold storage is more suitable for real-world application in the near future compared to the fluids for cold storage. A standalone LAES system with packed bed energy storage is proposed in our previous work. However, the utilization of pressurized air for heat transfer fluid in the cold storage packed bed (CSPB) is confusing, and the effect of the CSPB on the system level should be further discussed. To address these issues, the dynamic performance of the CSPB is analyzed with the physical properties of the selected cold storage materials characterized. The system simulation is conducted in an experiment scale with and without considering the exergy loss of the CSPB for comparison. The simulation results show that the proposed LAES system has an ideal round trip efficiency (RTE) of 39.38–52.91%. With the consideration of exergy destruction of the CSPB, the RTE decreases by 19.91%. Furthermore, increasing the cold storage pressure reasonably is beneficial to the exergy efficiency of the CSPB, whether it is non-supercritical (0.1 MPa–3 MPa) or supercritical (4 MPa–9 MPa) air. These findings will give guidance and prediction to the experiments of the LAES and finally promote the development of the industrial application.

On Thermal Energy Transport Complications in Chemically Reactive Liquidized Flow Fields Manifested with Thermal Slip Arrangements

Heat transfer systems for chemical processes must be designed to be as efficient as possible. As heat transfer is such an energy-intensive stage in many chemical processes, failing to focus on efficiency can push up costs unnecessarily. Many problems involving heat transfer in the presence of a chemically reactive species in the domain of the physical sciences are still unsolved because of their complex mathematical formulations. The same is the case for heat transfer in chemically reactive magnetized Tangent hyperbolic liquids equipped above the permeable domain. Therefore, in this work, a classical remedy for such types of problems is offered by performing Lie symmetry analysis. In particular, non-Newtonian Tangent hyperbolic fluid is considered in three different physical frames, namely, (i) chemically reactive and non-reactive fluids, (ii) magnetized and non-magnetized fluids, and (iii) porous and non-porous media. Heat generation, heat absorption, velocity, and temperature slips are further considered to strengthen the problem statement. A mathematical model is constructed for the flow regime, and by using Lie symmetry analysis, an invariant group of transformations is constructed. The order of flow equations is dropped down by symmetry transformations and later solved by a shooting algorithm. Interesting physical quantities on porous surfaces are critically debated. It is believed that the problem analysis carried out in this work will help researchers to extend such ideas to other unsolved problems in the field of heat-transfer fluid science.

Study and Feasibility of a Flat Collector Cooker using Vegetal Heat Transfer Fluid

Solar cookers currently produced are solar systems that use parabolic heat transfer to concentrate sun rays on a cooker. The new trend is focus on the cooker that uses a flat collector operating as a thermosiphon where the heat transfer fluid (oil) flows by natural convection. They are developed to address household needs at a lower cost, making them popular both in terms of research and use. Some of vegetable oils were previously investigated and which could be used as heat transfer fluids in such systems. A digital study using vegetable oil called "Kibi oil", an artisanal oil produced in Côte d’Ivoire, as a coolant, was conducted under poor weather conditions to calculate temperatures that could be reached in these cases. In the Sahelian zone, conditions are much better than these, and we can expect fairly excellent results. This study focused on temperature variation at different areas (1, 2, 3 and 4 specified in the diagram) of the cooker, on the mass flow of the fluid throughout the study day and to some quantities which enable to follow the performance of the solar collector of the stove. Sunlight measurements used are those of the city of Abidjan made in September, a very cloudy day with poor weather conditions. Temperature T3, very close to that of the hot plate, was around 110 °C between 10:30 am and 12:30 pm, which enables to cook certain dishes during this period. It should be noticed that at the exit of the flat panel collector, over the same period, the temperature is around 120 ° C. At that same time, the collector efficiency varies around 30%.

Improving the Performance of Solar Heat Collector Using Molten Salts

An individual solar collector and two partly freight cylinders filled with molten salts embedded storage tank were connected to each other and forced circulated water by electric pump to improve the thermal performance of residential solar hot water tank. Multi flow rates of 25, 50 and 70 l/h. used to achieve an appropriate flow rate of circulating water. The calcium nitrate tetra hydrate Ca(NO3)2-4H2O and magnesium nitrate hex hydrate Mg(NO3)2-6H2O were mixed to form cheap binary molten salts base on different weight ratios. These molten salts combined could be used as both sensible heat materials and latent heat storage materials, besides they can directly use as heat transfer fluid due to freezing temperature. Six samples of different mixing ratio of molten salts had tested to assess the thermal analysis of each sample. The result indicated that the mixture 60%Ca(NO3)2+40%Mg(NO3)2 had the best performance for thermal storage tank with melting point of 38°C and the thermal value is 8.7 mW, and thermal stability of molten salts were noticed by DSC 60 SHIMADZSU devise.

A Review on the Performance Indicators and Influencing Factors for the Thermocline Thermal Energy Storage Systems

Thermal energy storage (TES) system plays an essential role in the utilization and exploitation of renewable energy sources. Over the last two decades, single-tank thermocline technology has received much attention due to its high cost-effectiveness compared to the conventional two-tank storage systems. The present paper focuses on clarifying the performance indicators and the effects of different influencing factors for the thermocline TES systems. We collect the various performance indicators used in the existing literature, and classify them into three categories: (1) ones directly reflecting the quantity or quality of the stored thermal energy; (2) ones describing the thermal stratification level of the hot and cold regions; (3) ones characterizing the thermo-hydrodynamic features within the thermocline tanks. The detailed analyses on these three categories of indicators are conducted. Moreover, the relevant influencing factors, including injecting flow rate of heat transfer fluid, working temperature, flow distributor, and inlet/outlet location, are discussed systematically. The comprehensive summary, detailed analyses and comparison provided by this work will be an important reference for the future study of thermocline TES systems.

Integration of Concentrating Solar Heat into Oil and Gas Operations for Increased Sustainability

According to Eni's mission to reach carbon neutrality in the countries where it operates, the development of renewable energy could be a key element in the company's strategy for evolving the business model towards a low carbon scenario. In this context, concentrating solar technology can provide a real solution in order to goal the carbon neutrality. Solar thermal energy could be an alternative source to the fossil fuel in industrial processes and also in the oil&gas sector, where the upstream operations (dewatering, stabilization, sweetening…) require substantial amounts of heat. Usually this heat is easily produced by combustion of natural gas available at the oil&gas site. Concentrating Solar Heat (CSH) technology allows to produce process heat by using specific collectors that concentrate the solar radiation onto a receiver where a heat transfer fluid is heated at medium/high temperature. A thermal energy storage can be added to the solar field to increase the solar fraction and reducing so the CO2 emissions. The fraction of thermal energy not covered by the CSH plant can be provided by a fossil source that acts as a back-up. With this in mind, a pre-feasibility study was carried out for the integration of a medium temperature(∼200-300°C) concentrating solar plant with or without a thermal storage system and a back-up gas heater in an oil&gas site located in North Africa. The solar heat partially replaces the duty necessary to the heat exchangers that heat the crude to guarantee the separation from water and best stabilization. Reflective areas of the solar field and total occupancy, thermal energy production during the year, solar multiple and preliminary evaluations of cost of investment are presented. Obviously, the reduction of CO2 emission increases with the solar fraction but the competitiveness and cost-effectiveness of the integration strongly depend on the local cost of natural gas, the presence of government incentives, CO2 credit tax, etc. In any case the proposed solution represents an important step towards energy transition.

Thermal Characterization of Biofluids for Heat Transfer Fluid in Thermal Transport Technologies

Thermal fluids modulate temperature conditions around the thermal collector systems indirectly by circulating the heat transfer fluid throughout the heat exchanger, thereby simulating cooling and heating with thermal condition. This study investigates biofluid from Moringa oleifera kernel, Date kernel, Palm kernel, Coconut kernel and Mango kernel as base fluids for heat transfer fluid application in solar thermal technology. The methodology employed in this study is experimental and the analyzed biofluids results was compared with conventional heat transfer base fluids. Thermal constant analyzer (TPS-2005S), CT-72 Transparent viscometer and Eagle eye SG-500 portable digital hydrometer were used to measure the thermophysical properties, viscosity, and density, of the biofluids respectfully. From the results, the biofluids showed comparative thermophysical properties to conventional base fluids. Moringa oleifera kernel oil and Mango kernel oil has the best quality among the biofluids with thermal conductivity, specific heat, viscosity, and density value was 0.1698Wm/k, 1984.01J/kg.K, 37.12mm2/s, 874.23kg/m3, and 0.2642Wm/k, 763.18J/kg.K, 45.27mm2/s, 914.22kg/m3, respectively. The biofluids was thermally stable after exposure to several heating cycles and heating temperature as no significant degradation was observed in there thermophysical properties. However, there are needs for further experimental studies on clogging and possibility of enhancement of biofluids with organic nanoadditives.