Electrocatalytic oxidation and determination of dopamine in the presence of ascorbic acid and uric acid at a poly (p-nitrobenzenazo resorcinol) modified glassy carbon electrode

2007 ◽  
Vol 122 (1) ◽  
pp. 309-314 ◽  
Author(s):  
Xinhua Lin ◽  
Yafeng Zhang ◽  
Wei Chen ◽  
Ping Wu
Keyword(s):  
Ascorbic Acid ◽  
Uric Acid ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Electrocatalytic Oxidation ◽  
Carbon Electrode ◽  
Modified Glassy Carbon Electrode

Electrochemical studies of ascorbic acid, dopamine, and uric acid at a dl-norvaline-deposited glassy carbon electrode

2014 ◽  
Vol 92 (4) ◽  
pp. 329-336 ◽  
Author(s):  
Mahmoud Mohamed Kamel ◽  
Ehab Mahmoud Abdalla ◽  
Mohamed Sayed Ibrahim ◽  
Yassin Mohamed Temerk
Keyword(s):  
Ascorbic Acid ◽  
Uric Acid ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Differential Pulse ◽  
Carbon Electrode ◽  
Modified Glassy Carbon Electrode ◽  
Serum Samples ◽  
Solution Ph

The electrochemical behavior of ascorbic acid (AA), dopamine (DA), and uric acid (UA) on a dl-norvaline-modified glassy carbon electrode (GCE) was studied by cyclic voltammetry. The bare GCE failed to distinguish the oxidation peaks of AA, DA, and UA in phosphate-buffered solution (pH 5.0), while the dl-norvaline-modified GCE could separate them efficiently. In differential pulse voltammetric (DPV) measurements, the modified electrode resolved the overlapped voltammetric responses of AA, DA, and UA into three well-defined voltammetric peaks. Under optimum conditions, the anodic peak currents of DPV for AA, DA, and UA were proportional to the concentration in the range of 20–400, 1–40, and 15–180 μmol/L, respectively, with a correlation coefficient (r) of around 0.998. The detection limits were 5, 0.3, and 10 μmol/L (S/N = 3) for AA, DA, and UA, respectively. Satisfactory results were achieved for the determination of AA in vitamin C tablets, DA in a dopamine ampoule sample, and UA in human blood serum samples.

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