Simple flow injection for determination of sulfite by amperometric detection using glassy carbon electrode modified with carbon nanotubes–PDDA–gold nanoparticles

Talanta ◽  
2015 ◽  
Vol 133 ◽  
pp. 134-141 ◽  
Author(s):  
Maliwan Amatatongchai ◽  
Wongduan Sroysee ◽  
Sanoe Chairam ◽  
Duangjai Nacapricha
2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Negussie Negash ◽  
Hailemichael Alemu ◽  
Merid Tessema

Phenol and chlorophenols were investigated using single-wall carbon nanotubes (SWCNT) and poly(3,4-ethylenedioxythiophene) (PEDOT) composite modified glassy carbon electrode (SWCNT/PEDOT/GCE) as a detector in flow injection system. Optimization of experimental variables such as the detection potential, flow rate, and pH of the carrier solution (0.1 M sodium acetate) for the determination of phenol (P), 4-chlorophenol (CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP), and pentachlorophenol (PCP) were performed. Under these conditions, analytical parameters were calculated from the calibration curve of measured amperometric responses as a function of concentrations of phenol and chlorophenols. The designed electrode exhibited very good analytical performance. The designed electrode was tested with 20 repetitive injections of each analyte and showed good operational stability. The analytical performance of the SWCNT/PEDOT/GCE electrode under flow through conditions was tested and was found to be impressive. The electrode showed a wider dynamic range for the detection of phenol and chlorophenols with low limits of detection compared with other enzymatic and nonenzymatic sensors. These results suggest that the method is quite useful for the analysis and monitoring of phenols and chlorophenols.


2018 ◽  
Vol 185 (5) ◽  
Author(s):  
Jessica Scremin ◽  
Eduardo César Melo Barbosa ◽  
Carlos Alberto Rossi Salamanca-Neto ◽  
Pedro Henrique Cury Camargo ◽  
Elen Romão Sartori

The Analyst ◽  
1992 ◽  
Vol 117 (12) ◽  
pp. 1919-1923 ◽  
Author(s):  
Carolina Fernández ◽  
Elena Chico ◽  
Paloma Yáñez-Sedeño ◽  
José M. Pingarrón ◽  
Luis Ma. Polo

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