Alkyne hydrosilylation catalyzed by nickel complexes of N-heterocyclic carbenes

Tetrahedron ◽  
2006 ◽  
Vol 62 (32) ◽  
pp. 7560-7566 ◽  
Author(s):  
Mani Raj Chaulagain ◽  
Gireesh M. Mahandru ◽  
John Montgomery
Keyword(s):  
Nickel Complexes ◽  
Heterocyclic Carbenes ◽  
Alkyne Hydrosilylation

Alkyne Hydrosilylation Catalyzed by Nickel Complexes of N-Heterocyclic Carbenes.

ChemInform ◽  
2006 ◽  
Vol 37 (46) ◽  
Author(s):  
Mani Raj Chaulagain ◽  
Gireesh M. Mahandru ◽  
John Montgomery
Keyword(s):  
Nickel Complexes ◽  
Heterocyclic Carbenes ◽  
Alkyne Hydrosilylation

scholarly journals Hybrid Catalysts Comprised of Graphene Modified with Rhodium-Based N-Heterocyclic Carbenes for Alkyne Hydrosilylation

2020 ◽  
Vol 3 (2) ◽  
pp. 1640-1655 ◽  
Author(s):  
Beatriz Sánchez-Page ◽  
M. Victoria Jiménez ◽  
Jesús J. Pérez-Torrente ◽  
Vincenzo Passarelli ◽  
Javier Blasco ◽  
...  
Keyword(s):  
Heterocyclic Carbenes ◽  
Hybrid Catalysts ◽  
Alkyne Hydrosilylation

Nickel Complexes ofN-Heterocyclic Carbenes

2014 ◽  
pp. 371-396 ◽  
Author(s):  
M. Taylor Haynes ◽  
Evan P. Jackson ◽  
John Montgomery
Keyword(s):  
Nickel Complexes ◽  
Heterocyclic Carbenes

scholarly journals Nickel and palladium complexes of enolatefunctionalised N-heterocyclic carbenes

2010 ◽  
Vol 8 (5) ◽  
pp. 992-998 ◽  
Author(s):  
Saravanakumar Shanmuganathan ◽  
Olaf Kühl ◽  
Peter Jones ◽  
Joachim Heinicke
Keyword(s):  
Crystal Structure ◽  
Ionic Liquid ◽  
Nickel Complexes ◽  
Palladium Complexes ◽  
Heterocyclic Carbenes ◽  
Ethylene Oligomerization ◽  
Pure Form ◽  
Chloride Crystal ◽  
In Situ Techniques

AbstractThe reaction of chloroethyltrimethylsilylether with 1-methylimidazole furnishes an ionic liquid that undergoes methanolysis to crystalline 2-hydroxyethylimidazolium chloride (crystal structure presented). Conversion to defined hydroxyethylimidazol-2-ylidene nickel complexes failed, but was accomplished with 1-methyl-3-acetophenyl-imidazolium bromide. The bis(NHC⋂O−) nickel(II) chelate is formed, rather than a methallylnickel monochelate, but with nickelocene a monochelate NiCp complex was detected. The bulky 1-(2,6-diisopropylphenyl)-3-(2’-phenyl-enolato)-imidazol-2-ylidene allylpalladium chloride was obtained in pure form. Attempts to generate catalysts for ethylene oligomerization by in situ techniques have failed so far whereas P⋂O− ligands, comparable by the P-C diagonal relationship, provide active catalysts.

scholarly journals Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts

2008 ◽  
Vol 27 (2) ◽  
pp. 224-234 ◽  
Author(s):  
M. Victoria Jiménez ◽  
Jesús J. Pérez-Torrente ◽  
M. Isabel Bartolomé ◽  
Verena Gierz ◽  
Fernando J. Lahoz ◽  
...  
Keyword(s):  
Heterocyclic Carbenes ◽  
Alkyne Hydrosilylation

scholarly journals From betaines to anionic N-heterocyclic carbenes. Borane, gold, rhodium, and nickel complexes starting from an imidazoliumphenolate and its carbene tautomer

2016 ◽  
Vol 12 ◽  
pp. 2673-2681 ◽  
Author(s):  
Ming Liu ◽  
Jan C Namyslo ◽  
Martin Nieger ◽  
Mika Polamo ◽  
Andreas Schmidt
Keyword(s):  
Carbon Atom ◽  
Single Crystal ◽  
Nickel Complexes ◽  
Heterocyclic Carbenes

The mesomeric betaine imidazolium-1-ylphenolate forms a borane adduct with tris(pentafluorophenyl)borane by coordination with the phenolate oxygen, whereas its NHC tautomer 1-(2-phenol)imidazol-2-ylidene reacts with (triphenylphosphine)gold(I) chloride to give the cationic NHC complex [Au(NHC)2][Cl] by coordination with the carbene carbon atom. The anionic N-heterocyclic carbene 1-(2-phenolate)imidazol-2-ylidene gives the complexes [K][Au(NHC−)2], [Rh(NHC−)3] and [Ni(NHC−)2], respectively. Results of four single crystal analyses are presented.

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