Control of stereochemistry in atom transfer radical addition and step-growth radical polymerization by chiral transition metal catalysts

Tetrahedron ◽  
2016 ◽  
Vol 72 (48) ◽  
pp. 7657-7664 ◽  
Author(s):  
Takamasa Soejima ◽  
Kotaro Satoh ◽  
Masami Kamigaito
Keyword(s):  
Transition Metal ◽  
Radical Polymerization ◽  
Metal Catalysts ◽  
Radical Addition ◽  
Transition Metal Catalysts ◽  
Atom Transfer ◽  
Chiral Transition ◽  
Atom Transfer Radical Addition ◽  
Step Growth

Thermo-regulated phase separable catalysis (TPSC)-based atom transfer radical polymerization in a thermo-regulated ionic liquid

2014 ◽  
Vol 50 (66) ◽  
pp. 9266-9269 ◽  
Author(s):  
Xiangyang Du ◽  
Jinlong Pan ◽  
Mengting Chen ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Transition Metal ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Atom Transfer ◽  
Aget Atrp ◽  
First Time

A thermo-regulated phase separable catalysis (TPSC) system for AGET ATRP based on a thermo-regulated ionic liquid was developed for the first time. The corresponding transition metal catalysts could be easily recovered and reused several times with negligible loss of catalytic activity.

Sign in / Sign up

Export Citation Format

Share Document