Iterative step-growth synthesis and degradation of unimolecular polyviologens under mild conditions

An iterative step-growth addition method was used to expedite the gram-scale synthesis of main-chain polyviologens by several days, while also producing the longest main-chain polyviologen (i.e., 26 viologen subunits) reported...

A Literature Review on Supramolecular Devices

Supramolecular device includes hydrogel and polymer manufactured by gelation or polymerization. Hydrogels are produced via chemical and physical gelation. Polymers are synthesized through photopolymerization, step-growth, and chain-growth polymerization. The supramolecular device possesses as the host to entrap the guest molecules via chemical, physical and physical-chemical microencapsulation. The present review article discusses the microencapsulation techniques, mechanism of gelation or polymerization, and different gelation or polymerization methods with given examples, such as gelatin, chitosan, and polyvinyl alcohol (PVA), and polyamide to act as the hosts for encapsulation.

Selective solvent conditions influence sequence development and supramolecular assembly in step-growth copolymerization

Sequence control in synthetic copolymers remains a tantalizing objective in polymer science due to the influence of sequence on material properties and self-organization. A greater understanding of sequence development throughout the polymerization process will aid the design of simple, generalizable methods to control sequence and tune supramolecular assembly. In previous simulations of solution-based step-growth copolymerizations, we have shown that weak, non-bonding attractions between monomers of the same type can produce a microphase separation among the lengthening nascent oligomers and thereby alter sequence. This work explores the phenomenon further, examining how effective attractive interactions, mediated by a solvent selective for one of the reacting species, impact the development of sequence and the supramolecular assembly in a simple A-B copolymerization. We find that as the effective attractions between monomers increase, an emergent self-organization of the reactants causes a shift in reaction kinetics and sequence development. When the solvent-mediated interactions are selective enough, the simple mixture of A and B monomers oligomerize and self-assemble into structures characteristic of amphiphilic copolymers. The composition and morphology of these structures and the sequences of their chains are sensitive to the relative balance of affinities between the comonomer species. Our results demonstrate the impact of differing A-B monomer-solvent affinities on sequence development in solution-based copolymerizations and are of consequence to the informed design of synthetic methods for sequence controlled amphiphilic copolymers and their aggregates.