Aerobic cascade oxidation of substituted cyclopentane-1,2-diones using metalloporphyrin catalysts

Tetrahedron ◽  
2018 ◽  
Vol 74 (6) ◽  
pp. 661-664 ◽  
Author(s):  
Karolin Maljutenko ◽  
Victor Borovkov ◽  
Dzmitry Kananovich ◽  
Ivar Järving ◽  
Margus Lopp
Keyword(s):  
Metalloporphyrin Catalysts

Oxidation of 2-methylpyrroles with perchlorinated iron(III) metalloporphyrin catalysts: a versatile synthesis of symmetric and asymmetric dipyrromethanes

1998 ◽  
Vol 76 (10) ◽  
pp. 1467-1473 ◽  
Author(s):  
Veranja Karunaratne ◽  
David Dolphin
Keyword(s):  
Catalytic Oxidation ◽  
Allylic Alcohols ◽  
The Novel ◽  
Efficient Synthesis ◽  
Mild Conditions ◽  
Metalloporphyrin Catalysts

A variety of substituted 2-methylpyrroles (3-8) were oxidized using the metalloporphyrin catalysts iron(III) meso-tetra(2,6-dichloro-3-sulphonatophenyl)-β-octachloroporphyrin chloride 1 and iron(III) meso-tetra(2,6-dichlorophenyl)-β-octachloroporphyrin chloride 2 under very mild conditions. Treatment of the resulting allylic alcohols 3a-8a with α-free pyrroles 9 and 10 resulted in a very efficient synthesis of the corresponding dipyrromethanes 3b-8b and 3c-8c. Furthermore, the above allylic alcohols when treated with furfurylamine produced the novel (2-furylmethyl)-2-pyrrolylmethylamines 3d-8d.Key words: catalytic oxidation, metalloporphyrins, pyrroles, dipyrromethanes, polyhalogenated porphyrins.

Metalloporphyrin catalysts for living and immortal polymerizations

1996 ◽  
Vol 101 (1) ◽  
pp. 11-18 ◽  
Author(s):  
Shohei Inoue ◽  
Hiroshi Sugimoto ◽  
Takuzo Aida
Keyword(s):  
Metalloporphyrin Catalysts

Metalloporphyrin catalysts for organic synthesis

2004 ◽  
Vol 08 (09) ◽  
pp. 1166-1171 ◽  
Author(s):  
Gérard Simonneaux ◽  
Pietro Tagliatesta
Keyword(s):  
Organic Synthesis ◽  
Enantiomeric Excess ◽  
Catalytic Reactions ◽  
Terminal Alkynes ◽  
Asymmetric Oxidation ◽  
Carbene Transfer ◽  
Catalytic Asymmetric ◽  
Chiral Systems ◽  
Metalloporphyrin Catalysts

Novel chiral systems for the catalytic asymmetric oxidation and cyclopropanation of olefins based on metalloporphyrins containing iron, ruthenium and manganese, have been recently introduced. High catalyst turnover numbers and sometimes high enantiomeric excess were observed. New catalytic reactions with metalloporphyrins have recently been reported; these are the olefination of aldehydes and cyclotrimerization of terminal alkynes. Dendrimers and polymers containing metalloporphyrins, have also been found to be efficient catalysts for oxidation and carbene transfer.

scholarly journals Glutathione trapping of reactive drug metabolites produced by biomimetic metalloporphyrin catalysts

2015 ◽  
Vol 29 (19) ◽  
pp. 1849-1850
Author(s):  
Toni Lassila ◽  
Sampo Mattila ◽  
Miia Turpeinen ◽  
Ari Tolonen
Keyword(s):  
Drug Metabolites ◽  
Metalloporphyrin Catalysts

Cycloaddition Reaction of Propylene Oxide and Carbon Dioxide Over NaX Zeolite Supported Metalloporphyrin Catalysts

2014 ◽  
Vol 144 (11) ◽  
pp. 1894-1899 ◽  
Author(s):  
Fengyong Zhang ◽  
Yujia Xie ◽  
Pingle Liu ◽  
Fang Hao ◽  
Zhengjie Yao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Propylene Oxide ◽  
Cycloaddition Reaction ◽  
Nax Zeolite ◽  
Metalloporphyrin Catalysts

Polymer sulfofluoride films as carriers for metalloporphyrin catalysts

1991 ◽  
Vol 16 (1) ◽  
pp. 9-17 ◽  
Author(s):  
A.B. Solovieva ◽  
E.A. Lukashova ◽  
A.V. Vorobiev ◽  
S.F. Timashev
Keyword(s):  
Metalloporphyrin Catalysts

Enantioselective Epoxidation of Olefins with Chiral Metalloporphyrin Catalysts

ChemInform ◽  
2005 ◽  
Vol 36 (41) ◽  
Author(s):  
Eric Rose ◽  
Bruno Andrioletti ◽  
Samia Zrig ◽  
Melanie Quelquejeu-Etheve
Keyword(s):  
Enantioselective Epoxidation ◽  
Epoxidation Of Olefins ◽  
Metalloporphyrin Catalysts
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