Dual organic dyes as a pseudo-redox mediation system to promotion of tandem oxidation /[3+2] cycloaddition reactions under visible light

Tetrahedron ◽  
2021 ◽  
pp. 132166
Author(s):  
Mehdi Koohgard ◽  
Zeinab Hosseinpour ◽  
Mona Hosseini-Sarvari
Keyword(s):  
Visible Light ◽  
Organic Dyes ◽  
Cycloaddition Reactions ◽  
Mediation System

Rhodamines as Photocatalyst in Organic Synthesis

2020 ◽  
Vol 07 ◽  
Author(s):  
Avik K. Bagdi ◽  
Papiya Sikdar
Keyword(s):  
Visible Light ◽  
Organic Synthesis ◽  
Organic Dyes ◽  
Transition Metal Catalysts ◽  
Visible Light Photocatalysis ◽  
Eosin Y ◽  
Organic Transformations ◽  
The Sustainable Development ◽  
Mechanistic Pathway ◽  
Green Model

Abstract:: Organic synthesis under environment friendly conditions has great impact in the sustainable development. In this context, visible light photocatalysis has emerged as a green model as this offers an energy-efficient pathway towards the organic transformation. Different transition-metal catalysts (Ir-, Ru-, Cu- etc) and organic dyes (eosin Y, rose bengal, methylene blue etc) are well-known photocatalysts in organic synthesis. Apart from the well-known organophotoredox catalysts, rhodamines (Rhodamine B and Rhodamine 6G) have been also employed as efficient photocatalysts for different organic transformations. In this review, we will focus on the photocatalysis by rhodamines in organic synthesis. Mechanistic pathway of the methodologies will also be discussed. We believe this review will stimulate the employment of rhodamines in the visible light photocatalysis for efficient organic transformations in the future.

Photodegradation of organic dyes by PAN/SiO2-TiO2-NH2 nanofiber membrane under visible light

2019 ◽  
Vol 224 ◽  
pp. 509-514 ◽  
Author(s):  
Alaa Khalil ◽  
Nada M. Aboamera ◽  
Walaa S. Nasser ◽  
Walaa H. Mahmoud ◽  
Gehad G. Mohamed
Keyword(s):  
Visible Light ◽  
Organic Dyes ◽  
Nanofiber Membrane

A New Cycloaddition Profile for ortho-Quinone Methides: Photoredox-Catalyzed [6+4] Cycloadditions for Synthesis of Benzo[b]cyclopenta[e]oxepines

2022 ◽  
Author(s):  
Kenta Tanaka ◽  
Yosuke Asada ◽  
Yujiro Hoshino
Keyword(s):  
Visible Light ◽  
Cycloaddition Reactions ◽  
Quinone Methides

Visible-light-induced [6+4] cycloaddition reactions of ortho-quinone methides have been developed. The reaction of ortho-quinone methides with pentafulvenes in the presence of a thioxanthylium photoredox catalyst afforded benzo[b]cyclopenta[e]oxepines. The present reaction...

scholarly journals Applications of organocatalysed visible-light photoredox reactions for medicinal chemistry

2018 ◽  
Vol 14 ◽  
pp. 2035-2064 ◽  
Author(s):  
Michael K Bogdos ◽  
Emmanuel Pinard ◽  
John A Murphy
Keyword(s):  
Pharmaceutical Industry ◽  
Transition Metals ◽  
Visible Light ◽  
Reaction Mechanisms ◽  
General Class ◽  
Medicinal Chemistry ◽  
Organic Dyes ◽  
General Reaction ◽  
High Degree ◽  
Synthetic Medicinal

The focus of this review is to provide an overview of the field of organocatalysed photoredox chemistry relevant to synthetic medicinal chemistry. Photoredox transformations have been shown to enable key transformations that are important to the pharmaceutical industry. This type of chemistry has also demonstrated a high degree of sustainability, especially when organic dyes can be employed in place of often toxic and environmentally damaging transition metals. The sections are arranged according to the general class of the presented reactions and the value of these methods to medicinal chemistry is considered. An overview of the general characteristics of the photocatalysts as well as some electrochemical data is presented. In addition, the general reaction mechanisms for organocatalysed photoredox transformations are discussed and some individual mechanistic considerations are highlighted in the text when appropriate.

scholarly journals Copper’s rapid ascent in visible-light photoredox catalysis

Science ◽  
2019 ◽  
Vol 364 (6439) ◽  
pp. eaav9713 ◽  
Author(s):  
Asik Hossain ◽  
Aditya Bhattacharyya ◽  
Oliver Reiser
Keyword(s):  
Visible Light ◽  
Organic Dyes ◽  
Low Cost ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Photoredox Catalysis ◽  
Cross Coupling Reactions ◽  
Rapid Ascent ◽  
Catalyzed Reactions ◽  
Metal Catalyzed

Visible-light photoredox catalysis offers a distinct activation mode complementary to thermal transition metal catalyzed reactions. The vast majority of photoredox processes capitalizes on precious metal ruthenium(II) or iridium(III) complexes that serve as single-electron reductants or oxidants in their photoexcited states. As a low-cost alternative, organic dyes are also frequently used but in general suffer from lower photostability. Copper-based photocatalysts are rapidly emerging, offering not only economic and ecological advantages but also otherwise inaccessible inner-sphere mechanisms, which have been successfully applied to challenging transformations. Moreover, the combination of conventional photocatalysts with copper(I) or copper(II) salts has emerged as an efficient dual catalytic system for cross-coupling reactions.

Starfish-like Au–CdS hybrids for the highly efficient photocatalytic degradation of organic dyes

RSC Advances ◽  
2014 ◽  
Vol 4 (80) ◽  
pp. 42441-42444 ◽  
Author(s):  
Xinyu Wang ◽  
Yulong Ying ◽  
Jiahuan Lei ◽  
Pan Hu ◽  
Xinsheng Peng
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Au Nanoparticles ◽  
Organic Dyes ◽  
Highly Efficient ◽  
Self Assembling

A novel starfish-like Au–CdS heterostructures are constructed by a simple self-assembling method with centered Au nanoparticles, and exhibit highly efficient visible light photodegradation of organic dyes.

N-doped TiO2/s-PS aerogels for photocatalytic degradation of organic dyes in wastewater under visible light irradiation

2014 ◽  
Vol 89 (8) ◽  
pp. 1175-1181 ◽  
Author(s):  
Vincenzo Vaiano ◽  
Olga Sacco ◽  
Diana Sannino ◽  
Paolo Ciambelli ◽  
Simona Longo ◽  
...  
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Organic Dyes ◽  
Light Irradiation ◽  
Doped Tio2
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