Stereoselective total synthesis of (+)-cryptocarya diacetate by an iterative Jacobsen’s hydrolytic kinetic resolution protocol

2005 ◽  
Vol 46 (22) ◽  
pp. 3905-3907 ◽  
Author(s):  
Palakodety Radha Krishna ◽  
V.V. Ramana Reddy
Keyword(s):  
Total Synthesis ◽  
Kinetic Resolution ◽  
Hydrolytic Kinetic Resolution

First Stereoselective Total Synthesis of Anti-Inflammatory Metabolite­ Penicillinolide A

Synthesis ◽  
2018 ◽  
Vol 51 (06) ◽  
pp. 1427-1434 ◽  
Author(s):  
Palakodety Krishna ◽  
Mopuri Reddy ◽  
Gembali Manikanta
Keyword(s):  
Total Synthesis ◽  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Asymmetric Total Synthesis ◽  
Hydrolytic Kinetic Resolution ◽  
Anti Inflammatory ◽  
Key Steps

The first asymmetric total synthesis of penicillinolide A is described. Key steps of the synthesis involve Jacobsen’s hydrolytic kinetic resolution (HKR), chelation controlled allylation, Brown’s asymmetric allylation, hydroboration, and Yamaguchi lactonization.

A Versatile Co(bisalen) Unit for Homogeneous and Heterogeneous Cooperative Catalysis in the Hydrolytic Kinetic Resolution of Epoxides

2009 ◽  
Vol 15 (16) ◽  
pp. 3951-3955 ◽  
Author(s):  
Krishnan Venkatasubbaiah ◽  
Christopher S. Gill ◽  
Tait Takatani ◽  
C. David Sherrill ◽  
Christopher W. Jones
Keyword(s):  
Kinetic Resolution ◽  
Cooperative Catalysis ◽  
Hydrolytic Kinetic Resolution

Synthesis of the Neurokinin 1 Receptor Antagonist (+)-L-733,060 by Jacobsen’s Hydrolytic Kinetic Resolution

2020 ◽  
Vol 56 (12) ◽  
pp. 2159-2164
Author(s):  
D. N. Bhangare ◽  
V. B. Mahale ◽  
R. G. Shinde ◽  
M. D. Nikalje ◽  
S. D. Duthade ◽  
...  
Keyword(s):  
Receptor Antagonist ◽  
Kinetic Resolution ◽  
Neurokinin 1 Receptor ◽  
Hydrolytic Kinetic Resolution ◽  
Neurokinin 1
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