Diffusion and reaction in a fractal catalyst pore—III. Application to the simulation of vinyl acetate production from ethylene

1994 ◽  
Vol 49 (24) ◽  
pp. 4897-4907 ◽  
Author(s):  
Marc-Olivier Coppens ◽  
Gilbert F. Froment
Keyword(s):  
Vinyl Acetate ◽  
Acetate Production

scholarly journals OPTIMIZATION OF VINYL ACETATE PRODUCTION PROCESS

2021 ◽  
pp. 187-191
Author(s):  
Firdavsiy Buronov ◽  
Normurot Fayzullayev
Keyword(s):  
Production Process ◽  
Vinyl Acetate ◽  
Active Sites ◽  
Potassium Acetate ◽  
Vapour Phase ◽  
Kinetics And Mechanism ◽  
Total Rate ◽  
Acetate Production ◽  
Catalyst Efficiency

In the article, the kinetic laws and kinetics and mechanism of the oxidation acetylationreaction of ethylene in the vapour phase were studied in detail in a catalyst containing0,4%Рd+4%Cu+7%CH3COOK/HSZ. It was found that the total rate of the reaction was proportionalto the amount of unmodified and modified active sites of palladium (not clusters). Excess amountsof the modifier (both potassium acetate and copper) have been shown to block active sites byreducing catalyst efficiency.

Inhibition of Radical-Initiated Vinyl Acetate Polymerisation by Tobacco Smoke Fractions

1974 ◽  
Vol 7 (5) ◽  
Author(s):  
M.A. Nisbet ◽  
S. Schmeller
Keyword(s):  
Benzoyl Peroxide ◽  
Vinyl Acetate ◽  
Tobacco Smoke ◽  
Boiling Point ◽  
Water Bath ◽  
Measuring Time ◽  
Time Required

AbstractBoth the vapour and particulate phases of tobacco smoke have been shown to retard benzoyI-peroxide-initiated polymerisation of vinyl acetate by interception of the radicals involved in the polymerisation process. The extent of inhibition of polymerisation by test compounds is estimated by measuring time taken for a mixture of monomer and benzoyl peroxide, immersed in a water-bath at 70°C, to reach a spontaneous boil and comparing it with the time required for a similar mixture with added retarder to reach boiling point. Units are expressed as minutes of inhibition per part per million of inhibitor × 10

COMPARATIVE STUDIES OF ETHYLENE VINYL ACETATE FILMS WITH VARIOUS SILICATE NANOCOMPOSITES

2019 ◽  
Vol 12 (04) ◽  
pp. 1803-1809
Author(s):  
A. Kaviarasi ◽  
M.V.L. Kumari ◽  
A.R. Prabakaran ◽  
A. Anandavadivel
Keyword(s):  
Vinyl Acetate ◽  
Comparative Studies ◽  
Ethylene Vinyl Acetate ◽  
Silicate Nanocomposites
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