Temperature dependence of photoinduced electron transfer in hydrogen-bonded donor–acceptor systems

2001 ◽  
Vol 350 (1-2) ◽  
pp. 86-92 ◽  
Author(s):  
M.A Smitha ◽  
K.R Gopidas
2014 ◽  
Vol 18 (10n11) ◽  
pp. 982-990 ◽  
Author(s):  
Kei Ohkubo ◽  
Yuki Kawashima ◽  
Kentaro Mase ◽  
Hayato Sakai ◽  
Taku Hasobe ◽  
...  

An electron donor–acceptor supramolecular complex was formed between an anionic zinc chlorin carboxylate ( ZnCh -) and lithium-ion-encapsulated [60]fullerene ( Li +@ C 60) by an electrostatic interaction in benzonitrile ( PhCN ). Photoinduced electron transfer in the supramolecular complex of ZnCh -/ Li +@ C 60 resulted in the formation of the charge-separated state via electron transfer from the triplet excited state of ZnCh - to Li +@ C 60. We report herein photovoltaic cells using ZnCh -/ Li +@ C 60 nanoclusters, which are assembled on the optically transparent electrode (OTE) of nanostructured SnO 2 (OTE/ SnO 2). The photoelectrochemical behavior of the nanostructured SnO 2 film of supramolecular nanoclusters of ZnCh - and Li +@ C 60 denoted as OTE/ SnO 2/( ZnCh -/ Li +@ C 60)n is significantly higher than the single component films of ZnCh - or Li +@ C 60 clusters, denoted as OTE/ SnO 2/( ZnCh -)n or OTE/ SnO 2/( Li +@ C 60)n.


2020 ◽  
Vol 124 (7) ◽  
pp. 4010-4023 ◽  
Author(s):  
Ekaterina N. Ovchenkova ◽  
Natatiya G. Bichan ◽  
Arshak A. Tsaturyan ◽  
Nadezhda O. Kudryakova ◽  
Matvey S. Gruzdev ◽  
...  

2019 ◽  
Vol 55 (75) ◽  
pp. 11195-11198 ◽  
Author(s):  
Anton J. Stasyuk ◽  
Olga A. Stasyuk ◽  
Miquel Solà ◽  
Alexander A. Voityuk

Photoinduced electron transfer in CPP-based donor–acceptor complexes C60⊂[10]CPP and Li+@C60⊂[10]CPP was studied using DFT/TDDFT. Unusual blue shift of charge separated states for Li+@C60⊂[10]CPP complexes in the polar medium is predicted.


2001 ◽  
Vol 105 (17) ◽  
pp. 4172-4176 ◽  
Author(s):  
Gerald Zerza ◽  
Antonio Cravino ◽  
Helmut Neugebauer ◽  
N. Serdar Sariciftci ◽  
Rafael Gómez ◽  
...  

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