Electronic spectra, ESR and crystal structure of tetrahedral halocuprates(II). The existence of cations (2tbpo·H+) with a very short hydrogen bond

1983 ◽  
Vol 72 ◽  
pp. 127-131 ◽  
Author(s):  
Antonio Carlos Massabni ◽  
Otaciro Rangel Nascimento ◽  
Regina Helena De Almeida Santos ◽  
Regina Helena Porto Francisco ◽  
Johannes Rüdiger Lechat
Biochemistry ◽  
2011 ◽  
Vol 50 (45) ◽  
pp. 9836-9844 ◽  
Author(s):  
Keisuke Saito ◽  
Jian-Ren Shen ◽  
Toyokazu Ishida ◽  
Hiroshi Ishikita

The effect on the lattice spacings of substituting deuterium for hydrogen has been investigated for pentaerythritol, CuS0 4 5H 2 0, SrCl 2 6H 2 0, furmaric acid, KH 2 P0 4 , NaHS0 4 , urea, and KHF 2 . The main conclusion is that when the crystal structure contains hydroxyl bonds the isotope effect is small, and when it contains hydrogen bonds there is a marked expansion, which disturbs the lattice sufficiently to lead to the separation of potassium phosphate in a new crystal structure. The effect for potassium hydrogen fluoride does not suggest a short hydrogen bond in this compound. Short hydrogen bonds seem to require special resonance forces for their explanation.


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