Gas, solution, and solid state coordination environments for the nickel(II) complexes of a series of aminopyridine ligands of varying coordination number

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Richard W Vachet ◽  
John H Callahan
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Xuan Kan ◽  
Jian-Cheng Wang ◽  
Jing-Lan Kan ◽  
Jin-Yan Shang ◽  
Hua Qiao ◽  
...  

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Yudai Huang ◽  
Rongrong Jiang ◽  
Shu-Juan Bao ◽  
Yali Cao ◽  
Dianzeng Jia

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Amanda L Kammier ◽  
Robert J Spracklin ◽  
Wayne H Pearson ◽  
Marianny Y Combariza ◽  
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Alicia Glatfelter ◽  
Shi Bai ◽  
Olga Dmitrenko ◽  
Dale L. Perry ◽  
Scott E. Van Bramer ◽  
...  

Experimental and predicted 207Pb nuclear magnetic resonance (NMR) parameters of solid-state coordination complexes of lead(II) bromide, lead(II) iodide, and lead(II) chloride with 1,10-phenanthroline are reported. Structural and electronic differences between the 1:1 and 1:2 adducts are reflected by the NMR parameters. The NMR chemical shieldings of the isostructural complexes indicate that the electronic state of the lead(II) center depends on the number of ligands and the halogen anion. The NMR results suggest that the 1:2 adduct may be more stereochemically active than the 1:1 adduct.


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