The important role of an unpaired d-electron for terminal oxygen atom transfer reaction of the (hydroperoxo) iron(III) compound

Polyhedron ◽  
2003 ◽  
Vol 22 (2) ◽  
pp. 293-297 ◽  
Author(s):  
Yuzo Nishida ◽  
Sayo Ito ◽  
Satoshi Nishino
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


1981 ◽  
Vol 10 (11) ◽  
pp. 1639-1642 ◽  
Author(s):  
Shun’ichi Aida ◽  
Hiroyuki Ohta ◽  
Yoshio Kamiya

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