ChemInform Abstract: ROLE OF FERRYL (FEO2+) COMPLEXES IN OXYGEN ATOM TRANSFER REACTIONS. MECHANISM OF IRON(II) PORPHYRIN CATALYZED OXYGENATION OF TRIPHENYLPHOSPHINE

1980 ◽  
Vol 11 (47) ◽  
Author(s):  
D.-H. CHIN ◽  
G. N. LA MAR ◽  
A. L. BALCH
Keyword(s):  
Oxygen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Reactions Mechanism

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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