2,2':6',2''-Terpyridine metal complexes as building blocks for extended functional metallo-supramolecular assemblies and polymers

2001 ◽  
Vol 121 (1-3) ◽  
pp. 1249-1252 ◽  
Author(s):  
U.S. Schubert ◽  
C. Eschbaumer ◽  
P. Andres ◽  
H. Hofmeier ◽  
C.H. Weidl ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Building Blocks ◽  
Supramolecular Assemblies

Novel water soluble cationic Au(I) complexes with cyclic PNNP ligand as building blocks for heterometallic supramolecular assemblies with anionic hexarhenium cluster units

2018 ◽  
Vol 196 ◽  
pp. 485-491 ◽  
Author(s):  
Julia Elistratova ◽  
Igor Strelnik ◽  
Konstantin Brylev ◽  
Michael A. Shestopalov ◽  
Tatiana Gerasimova ◽  
...  
Keyword(s):  
Building Blocks ◽  
Supramolecular Assemblies ◽  
Water Soluble

1,10-Phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes

2009 ◽  
Vol 38 (6) ◽  
pp. 1690 ◽  
Author(s):  
Gianluca Accorsi ◽  
Andrea Listorti ◽  
K. Yoosaf ◽  
Nicola Armaroli
Keyword(s):  
Metal Complexes ◽  
Building Blocks

Symmetrical tetra-β″-sulfoleno-meso-aryl-porphyrins — synthesis, spectroscopy and structural characterization

2014 ◽  
Vol 18 (01n02) ◽  
pp. 115-122 ◽  
Author(s):  
Srinivas Banala ◽  
Klaus Wurst ◽  
Bernhard Kräutler
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Structural Characterization ◽  
Building Blocks ◽  
Cycloaddition Reactions ◽  
One Pot

We report here the preparation (in "one-pot") of a tetra-β″-sulfoleno-meso-aryl-porphyrin in about 80% yield by using an optimized modification of Lindsey's variant of the Adler–Longo approach. The Zn ( II )-, Cu ( II )- and Ni ( II )-complexes of the symmetrical porphyrin were prepared and characterized spectroscopically. Crystal structures of the fluorescent Zn ( II )- and of the non-fluorescent Ni ( II )-tetra-β″-sulfoleno-meso-aryl-porphyrinates showed the highly substituted porphyrin ligands to be nearly perfectly planar. The Zn ( II )-complex of this porphyrin has been used as a thermal precursor of a reactive diene, and — formally — of lateral and diagonal bis-dienes, of a tris-diene and of a tetra-diene, which all underwent [4 + 2]-cycloaddition reactions in situ with a range of dienophiles. Thus, the tetra-β″-sulfoleno-meso-aryl-porphyrin and its metal complexes represent reactive building blocks, "programmed" for the syntheses of symmetrical and highly functionalized porphyrins.

scholarly journals Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical nanomaterials

2022 ◽  
Author(s):  
Jamie M. Cameron ◽  
Geoffroy Guillemot ◽  
Theodor Galambos ◽  
Sharad S. Amin ◽  
Elizabeth Hampson ◽  
...  
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Supramolecular Materials ◽  
Inorganic Hybrid ◽  
Hierarchical Nanomaterials

Organic–inorganic hybrid polyoxometalates are versatile building blocks for the self-assembly of functional supramolecular materials.

Cation Modules as Building Blocks Forming Supramolecular Assemblies with Planar Receptor–Anion Complexes

2013 ◽  
Vol 135 (4) ◽  
pp. 1284-1287 ◽  
Author(s):  
Bin Dong ◽  
Tsuneaki Sakurai ◽  
Yoshihito Honsho ◽  
Shu Seki ◽  
Hiromitsu Maeda
Keyword(s):  
Building Blocks ◽  
Supramolecular Assemblies ◽  
Anion Complexes

Metal-polypyridyl complexes with pendant adenine and thymine groups as building blocks for hydrogen-bonded supramolecular assemblies

Polyhedron ◽  
1996 ◽  
Vol 15 (11) ◽  
pp. 1907-1911 ◽  
Author(s):  
Monica Fernandez Gonzalez ◽  
David A. Bardwell ◽  
John C. Jeffery ◽  
Michael D. Ward
Keyword(s):  
Building Blocks ◽  
Supramolecular Assemblies ◽  
Polypyridyl Complexes ◽  
Hydrogen Bonded
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