Characterization of a β-glycosidase highly active on disaccharides and of a β-galactosidase from Tenebrio molitor midgut lumen

2003 ◽  
Vol 33 (2) ◽  
pp. 253-265 ◽  
Author(s):  
Alexandre H.P Ferreira ◽  
Walter R Terra ◽  
Clélia Ferreira
2001 ◽  
Vol 28 (5) ◽  
pp. 405-415 ◽  
Author(s):  
Mary Kate Morris ◽  
David A. Katzenstein ◽  
Dennis Israelski ◽  
Andrew Zolopa ◽  
R. Michael Hendry ◽  
...  

2019 ◽  
Vol 43 (23) ◽  
pp. 8930-8938 ◽  
Author(s):  
Zahra Tashrifi ◽  
Saeed Bahadorikhalili ◽  
Hossein Lijan ◽  
Samira Ansari ◽  
Haleh Hamedifar ◽  
...  

A novel catalyst is synthesized based on the immobilization of palladium on γ-Fe2O3@SiO2–(CH2)3–PDTC nanoparticles and is used as a highly active catalyst for the Heck/Sonogashira coupling reactions.


2020 ◽  
Author(s):  
Joel D. Smith ◽  
George Durrant ◽  
Daniel Ess ◽  
Warren Piers

<div>The synthesis and characterization of an iridium polyhydride complex (Ir-H4)</div><div>supported by an electron-rich PCP framework is described. This complex readily loses molecular</div><div>hydrogen allowing for rapid room temperature hydrogen isotope exchange (HIE) at the hydridic</div><div>positions and the α-C-H site of the ligand with deuterated solvents such as benzene-d6, toluene-d8</div><div>and THF-d8. The removal of 1-2 equivalents of molecular H2 forms unsaturated iridium carbene</div><div>trihydride (Ir-H3) or monohydride (Ir-H) compounds that are able to create further unsaturation</div><div>by reversibly transferring a hydride to the ligand carbene carbon. These species are highly active</div><div>hydrogen isotope exchange (HIE) catalysts using C6D6 or D2O as deuterium sources for the</div><div>deuteration of a variety of substrates. By modifying conditions to influence the Ir-Hn speciation,</div><div>deuteration levels can range from near exhaustive to selective only for sterically accessible sites.</div><div>Preparative level deuterations of select substrates were performed allowing for procurement of</div><div>>95% deuterated compounds in excellent isolated yields; the catalyst can be regenerated by</div><div>treatment of residues with H2 and is still active for further reactions.</div>


1994 ◽  
Vol 6 (5) ◽  
pp. 611-613 ◽  
Author(s):  
Iain McCulloch ◽  
Hong-Tai Man ◽  
Brian Marr ◽  
C. C. Teng ◽  
Kigook Song

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