Extraction Equilibria of Trimellitic and [1,1′-Biphenyl]-2,2′-dicarboxylic Acid with 1-Octanol, 50%TBP, and 10%TRPO in Kerosene

2008 ◽  
Vol 16 (6) ◽  
pp. 867-870 ◽  
Author(s):  
Zhiyong ZHOU ◽  
Wei QIN ◽  
Youyuan DAI
Keyword(s):  
Dicarboxylic Acid ◽  
Extraction Equilibria

IR and 13C, 17O, and 119Sn NMR spectra of some bis(1-butyl)tin(IV) carboxylates of dicarboxylic acids

1991 ◽  
Vol 56 (9) ◽  
pp. 1908-1915 ◽  
Author(s):  
Jaroslav Holeček ◽  
Antonín Lyčka ◽  
Milan Nádvorník ◽  
Karel Handlíř
Keyword(s):  
Infrared Spectroscopy ◽  
Nmr Spectroscopy ◽  
Dicarboxylic Acid ◽  
Nmr Spectra ◽  
Dicarboxylic Acids ◽  
119Sn Nmr ◽  
Carboxylic Groups ◽  
Cyclic Oligomers ◽  
The Media ◽  
Oxygen Atoms

Infrared spectroscopy and multinuclear (13C, 17O, and 119Sn NMR spectroscopy have been used to study the structure of bis(1-butyl)tin(IV) carboxylates of dicarboxylic acids (1-C4H9)2. Sn(X(COO)2), where X = (CH2)n (n = 0-8), CH=CH (cis and trans) and C6H4 (ortho and para).The crystalline compounds are formed by linear or cyclic oligomers or polymers whose basic building units represent a grouping composed of the central tin atom substituted by two 1-butyl groups and coordinated with both oxygen atoms of two anisobidentate carboxylic groups derived from different molecules of a dicarboxylic acid. The environment of the tin atom has a shape of a trapezoidal bipyramid. When dissolvet in non-coordinating solvents, the compounds retain the oligomeric character with unchanged structure of environment of the central tin atom. In the media of coordinating solvents the bis(1-butyl)tin(IV) carboxylates of dicarboxylic acids form complexes whose central hexacoordinated tin atom binds two molecules of the solvent trough their donor atoms. Carboxylic groups form monodenate linkages in these complexes.

scholarly journals Strong Even/Odd Pattern in the Computed Gas-Phase Stability of Dicarboxylic Acid Dimers: Implications for Condensation Thermodynamics

2019 ◽  
Vol 123 (44) ◽  
pp. 9594-9599 ◽  
Author(s):  
Jonas Elm ◽  
Noora Hyttinen ◽  
Jack J. Lin ◽  
Theo Kurtén ◽  
Nønne L. Prisle
Keyword(s):  
Dicarboxylic Acid ◽  
Gas Phase ◽  
Phase Stability

A Convenient Preparation of 9H-Carbazole-3,6-dicarbonitrile and 9H-Carbazole-3,6-dicarboxylic Acid

Synthesis ◽  
2014 ◽  
Vol 46 (05) ◽  
pp. 596-599 ◽  
Author(s):  
Mohamed Eddaoudi ◽  
Łukasz Weseliński ◽  
Ryan Luebke
Keyword(s):  
Dicarboxylic Acid ◽  
Convenient Preparation

Ribosylierung mono- und bicyclischer Dicarbonsäureimide / Ribosylation of Mono- and Bicyclic Dicarboxylic Acid Imides

1988 ◽  
Vol 43 (5-6) ◽  
pp. 397-402
Author(s):  
Kurt-Peter Raezke ◽  
Hermann Frister ◽  
Eckhard Schlimme
Keyword(s):  
Nmr Spectroscopy ◽  
Dicarboxylic Acid ◽  
Phthalic Acid ◽  
Cyclic Imides ◽  
Tin Tetrachloride

The N-trimethylsilyl compounds of the cyclic imides derived from cis-cyclohexan-1,2-dicarboxylic acid, cis-4-cyclohexen-1,2-dicarboxylic acid and phthalic acid were prepared. Reaction of the N-silylated cyclic imides 2 and 10 with 1,2,3,5-tetra-O-acetyl-β-ᴅ-ribofuranose in the presence of tin tetrachloride yielded the appropriate unusual ribonucleosides 4 and 12 whereas 14 led only to traces of the ribosylated derivative. The silylation and ribosylation sites in the aforementioned bicyclic imides were proved by 1H, 13C, and 29Si NMR spectroscopy and compared with data found for the monocyclic imides N-succinimide and N-maleinimide.

scholarly journals Water Photo-Electrooxidation Using Mats of TiO2 Nanorods, Surface Sensitized by a Metal–Organic Framework of Nickel and 1,2-Benzene Dicarboxylic Acid

Hydrogen ◽  
2021 ◽  
Vol 2 (1) ◽  
pp. 58-75
Author(s):  
Sheng-Mu You ◽  
Waleed M. A. El Rouby ◽  
Loïc Assaud ◽  
Ruey-An Doong ◽  
Pierre Millet
Keyword(s):  
Dicarboxylic Acid ◽  
Electrochemical Impedance ◽  
Metal Organic Framework ◽  
Linear Sweep Voltammetry ◽  
Tio2 Nanorods ◽  
Tem Analysis ◽  
Vis Spectroscopy ◽  
Metal Organic ◽  
Benzene Dicarboxylic Acid ◽  
Organic Framework

Photoanodes comprising a transparent glass substrate coated with a thin conductive film of fluorine-doped tin oxide (FTO) and a thin layer of a photoactive phase have been fabricated and tested with regard to the photo-electro-oxidation of water into molecular oxygen. The photoactive layer was made of a mat of TiO2 nanorods (TDNRs) of micrometric thickness. Individual nanorods were successfully photosensitized with nanoparticles of a metal–organic framework (MOF) of nickel and 1,2-benzene dicarboxylic acid (BDCA). Detailed microstructural information was obtained from SEM and TEM analysis. The chemical composition of the active layer was determined by XRD, XPS and FTIR analysis. Optical properties were determined by UV–Vis spectroscopy. The water photooxidation activity was evaluated by linear sweep voltammetry and the robustness was assessed by chrono-amperometry. The OER (oxygen evolution reaction) photo-activity of these photoelectrodes was found to be directly related to the amount of MOF deposited on the TiO2 nanorods, and was therefore maximized by adjusting the MOF content. The microscopic reaction mechanism which controls the photoactivity of these photoelectrodes was analyzed by photo-electrochemical impedance spectroscopy. Microscopic rate parameters are reported. These results contribute to the development and characterization of MOF-sensitized OER photoanodes.

Efficient and Stable Perovskite Solar Cells Enabled by Dicarboxylic Acid-Supported Perovskite Crystallization

2021 ◽  
Vol 12 (3) ◽  
pp. 997-1004
Author(s):  
Ahmed Esmail Shalan ◽  
Erdi Akman ◽  
Faranak Sadegh ◽  
Seckin Akin
Keyword(s):  
Solar Cells ◽  
Dicarboxylic Acid ◽  
Perovskite Solar Cells
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