Further study on intramolecular hydrogen-atom transfer originating from the lowest excited triplet state of 2-methylbenzophenone

1998 ◽  
Vol 119 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Toshihiro Nakayama ◽  
Yukiyoshi Torii ◽  
Tetsuhiko Nagahara ◽  
Kumao Hamanoue
Keyword(s):  
Hydrogen Atom ◽  
Triplet State ◽  
Hydrogen Atom Transfer ◽  
Excited Triplet State ◽  
Atom Transfer ◽  
Excited Triplet ◽  
Intramolecular Hydrogen

scholarly journals Triplet state promoted reaction of SO2 with H2O by competition between proton coupled electron transfer (pcet) and hydrogen atom transfer (hat) processes

2019 ◽  
Vol 21 (19) ◽  
pp. 9779-9784 ◽  
Author(s):  
Josep M. Anglada ◽  
Marilia T. C. Martins-Costa ◽  
Joseph S. Francisco ◽  
Manuel F. Ruiz-López
Keyword(s):  
Electron Transfer ◽  
Hydrogen Atom ◽  
Triplet State ◽  
Electronic State ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Excited Triplet ◽  
Proton Coupled Electron Transfer

The excited triplet electronic state of SO2 (a3B1) reacts with water through a proton coupled electron transfer (pcet) mechanism rather than via a conventional hydrogen atom transfer (hat) process.

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