Tunneling rate constants for intramolecular hydrogen atom transfer reactions in solution

1996 ◽  
Vol 93 ◽  
pp. 1783-1807 ◽  
Author(s):  
S Lee ◽  
JT Hynes
Keyword(s):  
Hydrogen Atom ◽  
Rate Constants ◽  
Hydrogen Atom Transfer ◽  
Tunneling Rate ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions ◽  
Intramolecular Hydrogen

Hydrogen atom transfer reactions of ferrate(vi) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation

2016 ◽  
Vol 45 (1) ◽  
pp. 70-73 ◽  
Author(s):  
Jianhui Xie ◽  
Li Ma ◽  
William W. Y. Lam ◽  
Kai-Chung Lau ◽  
Tai-Chu Lau
Keyword(s):  
Hydrogen Atom ◽  
Rate Constant ◽  
Rate Constants ◽  
Hydrogen Atom Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Bond Strengths ◽  
Oxidation Of Phenols ◽  
Atom Transfer Reactions

The oxidation of phenols (X-CH6H4OH) and hydroquinone (H2Q) by HFeO4− proceeds via a hydrogen atom transfer (HAT) mechanism. The Marcus cross relation can be used to predict the rate constant of HAT from H2Q to HFeO4−.

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